SIMULATION OF RADIATION-CHEMICAL OXIDATION OF NP(IV) IN NITRIC-ACID SOLUTIONS

被引：0
|
作者：
VLADIMIROVA, MV
机构：
来源：
RADIOCHEMISTRY | 1995年 / 37卷 / 01期
关键词：
D O I：
暂无
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Simulation was performed of radiolytic behavior of Np(IV) in 0.7-6 M HNO3. Rate constants for the reactions Np(IV) + OH and Np(IV) + NO3 have been found by comparing experimental and simulated kinetic curves and radiation-chemical yields of Np(IV) oxidation. The mechanisms of the influence of HNO3 and Np(IV) concentrations and the irradiation dose rate on the efficiency of Np(IV) oxidation are discussed.
引用
收藏
页码：39 / 43
页数：5
相关论文
共 50 条
  • [41] KINETICS OF CE(IV) OXIDATION OF 3-BROMO PROPIONIC-ACID IN AQUEOUS NITRIC-ACID SOLUTIONS
    SINGH, B
    SAXENA, PK
    SHUKLA, RK
    KRISHNA, B
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1977, 54 (04) : 378 - 380
  • [42] EFFECT OF ALPHA-RADIATION ON ACTINIDE OXIDATION-STATES .8. RADIATION-CHEMICAL BEHAVIOR OF NP AND PU IN THE SYSTEM NP(IV)-PU(IV)-CM-HNO3
    ROTMANOV, KV
    ANDREICHUK, NN
    VASILEV, VY
    RADIOCHEMISTRY, 1993, 35 (04) : 484 - 491
  • [43] KINETICS AND MECHANISM OF OXIDATION OF THE AMMONIUM ION BY NITRIC-ACID SOLUTIONS
    KAZAKOV, AI
    ANDRIENKO, LP
    RUBTSOV, YI
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1980, 29 (05): : 681 - 685
  • [44] KINETICS OF THE OXIDATION OF CERIUM(III) BY OZONE IN NITRIC-ACID SOLUTIONS
    NIKITINA, GP
    EGOROVA, VP
    MIFTAKHUDINOVA, IK
    SOVIET RADIOCHEMISTRY, 1980, 22 (05): : 528 - 535
  • [45] OXIDATION OF PERFLUOROISOQUINOLINE WITH NITRIC-ACID
    SARTORI, P
    AHLERS, K
    FROHN, HJ
    JOURNAL OF FLUORINE CHEMISTRY, 1976, 8 (05) : 457 - 460
  • [46] OXIDATION OF BK(III) IN NITRIC-ACID SOLUTION AND STABILITY OF BK(IV)
    CHEPOVOI, VI
    LEBEDEV, IA
    KULYAKO, YM
    MYASOEDOV, BF
    SOVIET RADIOCHEMISTRY, 1980, 22 (05): : 499 - 502
  • [47] ABSORPTION-SPECTRA OF NP(III), (IV), (V) AND (VI) IN NITRIC-ACID SOLUTION
    FRIEDMAN, HA
    TOTH, LM
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1980, 42 (09): : 1347 - 1349
  • [48] OXIDATION OF PHOSPHORUS BY NITRIC-ACID
    NIKANDROV, IS
    ZAGURSKAYA, VV
    KIM, PP
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1978, 51 (09): : 1986 - 1987
  • [49] CYCLOHEXANOL OXIDATION BY NITRIC-ACID
    FREIDLIN, GN
    GOLUBKO, LA
    ENYUTINA, TM
    ZHURNAL PRIKLADNOI KHIMII, 1973, 46 (01) : 226 - 227
  • [50] KINETIC-STUDIES ON THE OXIDATION OF URANIUM(IV) IN NITRIC-ACID SOLUTION
    ZHOU, ZM
    ZHANG, YJ
    DU, HF
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS, 1994, 188 (03): : 177 - 187
12345