PREPARATION AND WITTIG REACTIVITY OF ORGANOTRANSITION-METAL-SUBSTITUTED PHOSPHONIUM SALTS

被引:12
|
作者
LEE, SG [1 ]
CHUNG, YK [1 ]
YOON, TS [1 ]
SHIN, W [1 ]
机构
[1] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151742,SOUTH KOREA
关键词
D O I
10.1021/om00032a001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of [(C6H6)Mn(CO)3]+ with CHR=PPh3 produces [(Ph3PCHR-eta5-C6H6)Mn(CO)3]+ (2). 2 reacts with LDA to produce a manganese-substituted ylide, which reacts with aldehydes to yield substituted olefinic compounds 3 and after oxidation to yield compound 6.
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页码:2873 / 2875
页数:3
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