PREPARATION AND WITTIG REACTIVITY OF ORGANOTRANSITION-METAL-SUBSTITUTED PHOSPHONIUM SALTS

被引：12

作者：

LEE, SG ^{[1
]}

CHUNG, YK ^{[1
]}

YOON, TS ^{[1
]}

SHIN, W ^{[1
]}

机构：

[1] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151742,SOUTH KOREA

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 08期

关键词：

D O I：

10.1021/om00032a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [(C6H6)Mn(CO)3]+ with CHR=PPh3 produces [(Ph3PCHR-eta5-C6H6)Mn(CO)3]+ (2). 2 reacts with LDA to produce a manganese-substituted ylide, which reacts with aldehydes to yield substituted olefinic compounds 3 and after oxidation to yield compound 6.

引用

页码：2873 / 2875

页数：3

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