INSIGHT INTO THE PORE STRUCTURE OF ZEOLITE MCM-22 THROUGH CATALYTIC TESTS

被引:0
|
作者
CORMA, A
CORELL, C
MARTINEZ, A
PEREZPARIENTE, J
机构
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The pore structure of the new high-silica MCM-22 zeolite is discussed on the bases of product selectivities obtained in four model reactions, i.e., isomerization of m-xylene, toluene alkylation, hydroisomerization of n-decane, and n-heptane cracking. MCM-22 was seen to present characteristics of both 10MR and 12MR zeolites depending on the particular criterion used. This peculiar behavior was explained assuming the co-existence of both type of channels in the pore structure of MCM-22.
引用
收藏
页码:859 / 866
页数:8
相关论文
共 50 条
  • [31] ZEOLITE MCM-22 - SYNTHESIS, DEALUMINATION AND STRUCTURAL CHARACTERIZATION
    UNVERRICHT, S
    HUNGER, M
    ERNST, S
    KARGE, HG
    WEITKAMP, J
    [J]. ZEOLITES AND RELATED MICROPOROUS MATERIALS: STATE OF THE ART 1994, 1994, 84 : 37 - 44
  • [32] Influence of zinc oxide on the crystallization of zeolite MCM-22
    Wu, JM
    Li, N
    Yang, YL
    Xiang, SH
    [J]. CHINESE JOURNAL OF CATALYSIS, 2004, 25 (06) : 427 - 428
  • [33] Effective ONIOM schemes for modeling MCM-22 zeolite
    Li, Yan
    Guo, Wenping
    Yuan, Shuping
    Fan, Weibin
    Wang, Jianguo
    Jiao, Haijun
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2009, 916 (1-3): : 53 - 60
  • [34] Modification of MCM-22 zeolite through sequential post-synthesis treatments. Implications on the acidic and catalytic behaviour
    Machado, V.
    Rocha, J.
    Carvalho, A. P.
    Martins, A.
    [J]. APPLIED CATALYSIS A-GENERAL, 2012, 445 : 329 - 338
  • [35] Synthesis of ferrisilicate with the MCM-22 structure
    Wu, P
    Lin, H
    Komatsu, T
    Yashima, T
    [J]. CHEMICAL COMMUNICATIONS, 1997, (07) : 663 - 664
  • [36] Zeolite MCM-22 Modified with Au and Cu for Catalytic Total Oxidation of Methanol and Carbon Monoxide
    Kaminski, Piotr
    Sobczak, Izabela
    Decyk, Piotr
    Ziolek, Maria
    Roth, Wieslaw J.
    Campo, Betiana
    Daturi, Marco
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (05): : 2147 - 2159
  • [37] Evaluation of the pore structure of MCM-22, MCM-36 and ITQ-2 materials using the n-decane catalytic test
    Pergher, SBC
    Corma, A
    Fornés, V
    [J]. QUIMICA NOVA, 2003, 26 (06): : 828 - 831
  • [38] Textural and catalytic properties of MCM-22 zeolite crystallized by the vapor-phase transport method
    Inagaki, S
    Kamino, K
    Hoshino, M
    Kikuchi, E
    Matsukata, M
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (06) : 1249 - 1254
  • [39] Effects of alcohol as organic auxiliary chemical on textural property and catalytic performance of MCM-22 zeolite
    State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
    [J]. Huaxue Fanying Gongcheng Yu Gongyi, 2008, 3 (234-239):
  • [40] Textural and catalytic properties of MCM-22 zeolite crystallized by the vapor-phase transport method
    [J]. Inagaki, S. (sinagaki_dr@ruri.waseda.jp), 1600, Chemical Society of Japan (77):