ELECTROPHILIC PHENYLSELENENYLATION OF THIOPHENES - SYNTHESIS OF POLY(PHENYLSELENO)THIOPHENES

被引：13
|
作者：
TIECCO, M
TESTAFERRI, L
TINGOLI, M
MARINI, F
MARIGGIO, S
机构：
[1] Istituto di Chimica Organica. Università di Perugia
来源：
TETRAHEDRON | 1994年 / 50卷 / 35期
关键词：
D O I：
10.1016/S0040-4020(01)89595-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The phenylselenenyl sulfate, generated from the oxidation of diphenyl diselenide with ammonium persulfate, easily effects electrophilic aromatic substitution reactions on thiophene, 2-and 3-methylthiophenes and on 3-bromothiophene. The phenylseleno group activates the substrate to further substitution. Under controlled experimental conditions, it is thus possible to introduce the desired number of phenylseleno groups into the thiophene ring.
引用
收藏
页码：10549 / 10554
页数：6
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