ALPHA-DEUTERIUM ISOTOPE EFFECTS IN THE THERMOLYSIS OF BETA-HYDROXY ESTERS

被引：6

作者：

QUIJANO, J ^{[1
]}

RESTREPO, I ^{[1
]}

GALLEGO, LH ^{[1
]}

YEPES, MD ^{[1
]}

机构：

[1] UNIV ANTIOQUIA,DEPT QUIM,MEDELLIN,COLOMBIA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76954-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha secondary isotope effects are determined experimentally by thermolysis of beta-hydroxyesters. These results are compatible with a change of hybridization of carbon-2 from reactant to transition state (sp(3) - sp(2)).

引用

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页码：4735 / 4738

页数：4

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