SYNTHESIS AND FLUORESCENCE PROPERTIES OF SELECTIVELY METALATED DIPORPHYRINS WITH ELECTRON-ACCEPTING MOIETIES

被引：41
|
作者：
NAGATA, T
机构：
[1] Department of Chemistry, Faculty of Science, Kyoto University, Kyoto
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 10期
关键词：
D O I：
10.1246/bcsj.64.3005
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthesis of selectively metallated diporphyrins with electron-accepting moieties is described. Steady-state fluorescence spectra of these compounds showed substantial quenching of the fluorescence of the free-base porphyrin. A possible ''superexchange'' mechanism of long-range electron transfer is discussed.
引用
收藏
页码：3005 / 3016
页数：12
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