STUDIES ON THERMOTROPIC LIQUID-CRYSTALLINE POLYMERS .5. SYNTHESIS AND PROPERTIES OF POLY(ETHER AMIDE)S

被引:10
|
作者
LIANG, AL
HSU, KY
CHANG, TC
机构
[1] CHUNG YUAN CHRISTIAN UNIV,DEPT CHEM ENGN,CHUNGLI 32023,TAIWAN
[2] NANYA JR COLL TECHNOL,CHUNGLI 32034,TAIWAN
关键词
D O I
10.1016/0014-3057(92)90083-E
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two series of poly(ether amide)s, I and II, were prepared by direct polycondensation from 4,4'-diacrylic acid-alpha, omega-diphenoxyalkanes and 4,4'-dicarboxyl-alpha, omega-diphenoxyalkanes with diamines. The phase behaviour of these polymers was studied by differential scanning calorimetry and optical polarizing microscopy using a heated stage. Poly(ether amide) IId showed thermotropic liquid crystalline behaviour by observation under the optical polarizing microscope but poly(ether amide)s I and II did not exhibit thermotropic liquid crystallinity unambiguously. It is suggested that these results are due to interchain hydrogen bonds.
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页码:783 / 789
页数:7
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