INTERACTION OF CCL4 WITH THE SURFACE OF AMORPHOUS ICE

被引：36

作者：

BLANCHARD, JL ^{[1
]}

ROBERTS, JT ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

LANGMUIR | 1994年 / 10卷 / 09期

关键词：

D O I：

10.1021/la00021a064

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature programmed desorption of CCl4 from amorphous ice films is described. Two distinct desorption states are observed, near 130 and 145 K. In contrast to most thermal desorption systems, the lower temperature state fills exclusively at low coverages, followed by the 145 K state at higher coverages. The two states are assigned to thermal desorption of CCl4 from ice and to sublimation of the condensed CCl4 phase, respectively. Both the frequency factor and the activation energy for CCl4 desorption from ice are greater than the frequency factor and activation energy for CCl4 sublimation. This difference is attributed to hydrophobic interactions between adsorbed CCl4 and the underlying ice layer.

引用

页码：3303 / 3310

页数：8

共 50 条

[31] The interaction of CH3Cl, CH2Cl2, CHCl3, and CCl4 with ozone on the surface of ice under stratospheric conditions
T. A. Vysokikh
D. F. Mukhamedzyanova
T. V. Yagodovskaya
S. V. Savilov
V. V. Lunin
Russian Journal of Physical Chemistry A, 2007, 81 : 1836 - 1839
[32] The interaction of CH3Cl, CH2Cl2, CHCl3, and CCl4 with ozone on the surface of ice under stratospheric conditions
Vysokikh, T. A.
Mukhamedzyanova, D. F.
Yagodovskaya, T. V.
Savilov, S. V.
Lunin, V. V.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 81 (11) : 1836 - 1839
[33] Interactions of CCl4 with thin D2O amorphous ice films.: 2.: Variation of desorption kinetics with ice preparation conditions and evidence for distinct structures of low-density amorphous ice
Sadtchenko, V
Knutsen, K
Giese, CF
Gentry, WR
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (20): : 4894 - 4902
[34] MECHANISM OF THE LETHAL INTERACTION OF CHLORDECONE AND CCL4 AT NON-TOXIC DOSES
MEHENDALE, HM
TOXICOLOGY LETTERS, 1989, 49 (2-3) : 215 - 241
[35] The formation of CCl4 from the elements
Stock, A
Lux, H
Wustrow, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1931, 195 (2/3): : 149 - 157
[36] MECHANISM OF CCL4 INDUCED HEPATOTOXICITY
GANS, H
PRABHUDESAI, M
BABB, J
BILLING, P
YAMAGUCHI, Y
GASTROENTEROLOGY, 1981, 80 (05) : 1333 - 1333
[37] CCL4 Signaling in the Tumor Microenvironment
Mukaida, Naofumi
Sasaki, So-ichiro
Baba, Tomohisa
TUMOR MICROENVIRONMENT: THE ROLE OF CHEMOKINES, PT A, 2020, 1231 : 23 - 32
[38] ROLE OF CCL4 IN METHANE CHLORINATION
SHREIBERT, AI
LITINSKII, AO
ZHURNAL FIZICHESKOI KHIMII, 1975, 49 (09): : 2392 - 2393
[39] Preparation of nanocrystalline ceria in CCl4
Wang, CY
Zhang, WY
Qian, YT
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2002, 94 (2-3): : 170 - 175
[40] REACTIONS OF (SILYLAMINO)PHOSPHINES WITH CCL4
WISIANNEILSON, P
FORD, RR
LI, BL
NEILSON, RH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 183 (MAR): : 147 - INOR

← 1 2 3 4 5 →