THE BRONSTED ACID-CATALYZED HYDROLYSIS OF ACYL FLUORIDES IN AQUEOUS-MEDIA - EVIDENCE FOR 2 MECHANISMS

被引：4
|
作者：
MOTIE, RE
SATCHELL, DPN
WASSEF, WN
机构：
[1] King's College, London WC2R 2LS, Strand
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 06期
关键词：
D O I：
10.1039/p29920000859
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In dioxane-water mixtures rich in dioxane the hydrolysis of benzoyl fluoride is shown to exhibit two mechanisms of acid catalysis: one at low, and one at high values of [H3O+]; only the second mechanism (A1) is detectable in pure water.
引用
收藏
页码：859 / 860
页数：2
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