Bis(mu(2) isopropylimido-kappa(2) N:N) bis[(eta(5) cyclopentadienyl)(ethenolato- kappa O)titanium(IV)]

被引：1

作者：

Haehnel, Martin ^{[1
]}

Spannenberg, Anke ^{[1
]}

Rosenthal, Uwe ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse E, Albert Einstein Str 29A, D-18059 Rostock, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

D O I：

10.1107/S1600536813033072

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)(mu(2)-N-iPr)](2) (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each Ti-IV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry.

引用

页码：M16 / +

页数：8

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