Bis(mu(2) isopropylimido-kappa(2) N:N) bis[(eta(5) cyclopentadienyl)(ethenolato- kappa O)titanium(IV)]

被引：1
|
作者：
Haehnel, Martin [1 ]
Spannenberg, Anke [1 ]
Rosenthal, Uwe [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse E, Albert Einstein Str 29A, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536813033072
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)(mu(2)-N-iPr)](2) (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each Ti-IV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry.
引用
收藏
页码：M16 / +
页数：8
相关论文
共 50 条
  • [1] Di-mu-oxido-bis[bis(diisopropylacetamidinato)-kappa N;kappa N-2,N'-germanium(IV)]
    Syre, Ronny
    Frenzel, Nancy
    Hrib, Cristian G.
    Burte, Edmund P.
    Jones, Peter G.
    Edemann, Frank T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M686 - +
  • [2] {N, N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl] methylamine-kappa(2) P, P'}bis(eta(5)-cyclopentadienyl) titanium(II)
    Haehnel, Martin
    Hansen, Sven
    Spannenberg, Anke
    Beweries, Torsten
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M346 - +
  • [3] BIS(MU-BENZOATO-KAPPA-O-KAPPA-O'-BIS[(BENZOATO-KAPPA(2)O,O')(N,N-DIMETHYLFORMAMIDE-KAPPA-O)-DIOXOURANIUM(VI)]
    NAVAZA, A
    IROULART, MG
    NIERLICH, M
    LANCE, M
    VIGNER, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1767 - 1770
  • [4] Bis[2-(benzyliminomethyl)pyrrol-1-ido-kappa N-2,N ']bis(dimethylamido-kappa N)-titanium(IV)
    Chen, Zhou
    Liu, Yonglu
    Li, Yahong
    Hu, Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M573 - +
  • [5] Bis(mu-diisopropylhydoxylaminato)-kappa O-2:N; kappa O-2:O-bis[(diisopropylhydoxylaminato-kappa O) beryllium]
    Berger, Raphael Johann Friedrich
    Jana, Surajit
    Monkowius, Uwe
    Mitzel, Norbert Werner
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1463 - +
  • [6] Bis(acetato-kappa O)bis(2-pyridinealdoxime kappa(2) N, N') cadmium
    Shirvan, Sadif A.
    Dezfuli, Sara Haydari
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1080 - +
  • [7] Bis(diethylamido-kappa N)(diethylamine-kappa N)-bis(2,6-diisopropylphenylamido-kappa N)-zirconium(IV)
    Zauliczny, Mateusz
    Grubba, Rafal
    Ponikiewski, Lukasz
    Pikies, Jerzy
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M72 - +
  • [8] Crystal structure of bis(mu-2-benzoylbenzoato-kappa O-2:O')bis[bis(2,2'-bipyridine-kappa N-2,N')manganese(II)] bis(perchlorate)
    Kani, Ibrahim
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M265 - U414
  • [9] Bis(mu-hydroxido-kappa O-2:O)bis[bis(5-carboxypyridine-2-carboxylato-kappa N-2,O-2)iron(III)] dihydrate
    Cao, Wenhai
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M625 - +
  • [10] Crystal structure of bis{mu(2)-[(2-iminocyclopentylidene)methylidene]azanido-kappa N-2:N '}bis[(eta(5)-pentamethylcyclopentadienyl)zirconium(IV)] hexane monosolvate
    Becker, Lisanne
    Spannenberg, Anke
    Arndt, Perdita
    Rosenthal, Uwe
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M219 - U178
12345