DIALKOXYOSMIUM(IV) PORPHYRINS - CRYSTAL AND MOLECULAR-STRUCTURES OF IETHOXY, DIPHENOXY, AND BIS(2-PROPANOLATO) (MESO-TETRAPHENYLPORPHYRINATO)OSMIUM(IV)

被引：26

作者：

CHE, CM ^{[1
]}

HUANG, JS ^{[1
]}

LI, ZY ^{[1
]}

POON, CK ^{[1
]}

TONG, WF ^{[1
]}

LAI, TF ^{[1
]}

CHENG, MC ^{[1
]}

WANG, CC ^{[1
]}

WANG, Y ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 25期

关键词：

D O I：

10.1021/ic00051a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of dialkoxyosmium(IV) porphyrins [Os(Por)(OR)2] [Por = TPP (meso-tetraphenylporphyrinato dianion), (MeO)12TPP (meso-tetrakis(3,4,5-trimethoxyphenyl)porphyrinato dianion); R = Me, Et, i-Pr, PhCH2] were synthesized by treatment of [Os(Por)(N2)(THF)] [Por = TPP, (MeO)12TPP] with alcohols in tetrahydrofuran (THF). All these new complexes were characterized by UV-visible, IR, and H-1 NMR spectroscopy. The X-ray crystal structures of [Os(TPP)(OEt)2], [Os(TPP)(OCH(CH3)2)2], and [Os(TPP)(OPh)2] have been determined: [Os(TPP)(OEt)2], monoclinic P2(1)/c, a = 9.858 (1) angstrom, b = 15.646 (4) angstrom, c = 13.137 (2) angstrom, beta = 106.94 (1)-degrees, Z = 2; [Os(TPP)(OCH(CH3)2)2], triclinic P1BAR, a = 9.812 (1) angstrom, b = 11.093 (1) angstrom, c = 11.656 (1) angstrom, a = 70.83 (1)-degrees, beta = 76.08-degrees, gamma = 62.06 (1)-degrees, Z = 1; [Os(TPP)(OPh)2], triclinic P1BAR, a = 10.253 (1) angstrom, b = 10.724 (1) angstrom, c = 11.958 (1) angstrom, alpha = 62.08 (1)-degrees, beta = 68.55 (1)-degrees, gamma = 79.30 (1)-degrees, Z = 1. The RO-Os-OR axes in all complexes are required to be linear by symmetry with Os-OR distances ranging from 1.909 (4) to 1.938 (2) angstrom, indicating the presence of dpi(Os)-ppi(O) interactions. The Os-O-C angles for the three complexes are nearly the same, being 127.0 (3)-128.2 (5)-degrees.

引用

下载

页码：5220 / 5225

页数：6

共 50 条

[31] SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURES OF POTASSIUM BIS(MU-HYDROXO)BIS[DINITRITOPLATINATE(II)] SESQUIHYDRATE AND POTASSIUM CYCLO-TRIS(MU-3-OXO-1-2-4,1-3-4-2-3-4)TRIS[DINITRITOPLATINATE(II)]TRINITRITOPLATINATE(IV) TRIHYDRATE
MIN, D
LARSEN, RD
EMERSON, K
ABBOTT, EH
INORGANIC CHEMISTRY, 1990, 29 (01) : 73 - 76
[32] SECONDARY BONDING .13. ARYL-TELLURIUM(IV) AND ARYL-IODINE(III) ACETATES AND TRIFLUOROACETATES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF BIS-(PARA-METHOXYPHENYL)TELLURIUM DIACETATE, MU-OXO-BIS[DIPHENYLTRIFLUOROACETOXYTELLURIUM] HYDRATE, AND (BIS(TRIFLUOROACETOXY)IODO]BENZENE
ALCOCK, NW
HARRISON, WD
HOWES, C
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (08): : 1709 - 1716
[33] SYNTHESIS, MOLECULAR-STRUCTURES, AND SOLUTION-PHASE BEHAVIOR OF NEW ANIONIC PENTACOORDINATE TRIORGANOTIN(IV) COMPOUNDS - TRIS(DIMETHYLAMINO)SULFONIUM DICHLOROTRIORGANOSTANNATES, BIS(2,6-DIMETHYLPHENOXY)TRIORGANOSTANNATES, AND CHLORO(2,6-DIMETHYLPHENOXY)TRIORGANOSTANNATES
SUZUKI, M
SON, IH
NOYORI, R
MASUDA, H
ORGANOMETALLICS, 1990, 9 (12) : 3043 - 3053
[34] OXIDATIVE-ADDITION REACTIONS OF MOLECULAR DIIODINE AND DIBROMINE TO DIVALENT ORGANOTIN COMPOUNDS - CRYSTAL-STRUCTURES OF BIS[8-(DIMETHYLAMINO)-1-NAPHTHYL]TIN(IV) DIBROMIDE AND (2,6-[BIS(DIMETHYLAMINO)METHYL]PHENYL)-(4-TOLYL)TIN(IV) DIODIDE
JASTRZEBSKI, JTBH
VANDERSCHAAF, PA
BOERSMA, J
VANKOTEN, G
DEWIT, M
WANG, YF
HEIJDENRIJK, D
STAM, CH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 407 (03) : 301 - 311
[35] THE 1ST AUTHENTICATED EXAMPLE OF GEOMETRICAL-ISOMERS IN ORGANOTIN(IV) COORDINATION CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF OCTAHEDRAL CIS-SNR2 AND TRANS-SNR2 ISOMERIC ADDUCTS OF DICHLOROBIS(4-CHLOROPHENYL)TIN(IV) WITH 4,4'-DIMETHYL-2,2'-BIPYRIDYL
DAS, VGK
KEONG, YC
WEI, C
SMITH, PJ
MAK, TCW
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (01): : 129 - 137
[36] CRYSTAL AND MOLECULAR STRUCTURES OF DI-MU-OXO/BIS(DIACETYLACETONATOTITANIUM(IV))-BISDIOXANE, (TIO)C5H7O2)2)2.2C4H8O2, AND DI-MU-OXO-BIS(DIACETYLACETONATOTITANIUM(IV)), (TIO(C5H7O2)2)2
SMITH, GD
CAMPBELL, JA
CAUGHLAN, CN
INORGANIC CHEMISTRY, 1972, 11 (12) : 2989 - &
[37] THE TRANS-STRENGTHENING OF THE SN-O BOND IN 6-COORDINATED COMPLEXES OF TIN(IV) - CRYSTAL AND MOLECULAR-STRUCTURES OF SNI4.2DPSO AND C2H5SNI3.2DPSO
JATSENKO, AV
MEDVEDEV, SV
PASESHNITCHENKO, KA
ASLANOV, LA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 284 (02) : 181 - 188
[38] CRYSTAL AND MOLECULAR-STRUCTURES OF BIS(TETRAPHENYLARSONIUM) TRIS(1,2-DICYANOETHYLENEDITHIOLATO)MOLYBDENATE(IV), [(C6H5)4AS]2[MO(MNT)3], AND ITS TUNGSTEN ANALOG [(C6H5)4AS]2[W(MNT)3]
BROWN, GF
STIEFEL, EI
INORGANIC CHEMISTRY, 1973, 12 (09) : 2140 - 2147
[39] SULFUR DICHLORIDE AS A LIGAND - THE MOLECULAR AND CRYSTAL-STRUCTURES OF TRANS-BIS (DICHLORSULFAN) PLATIN(IV) CHLORIDE PTCL4(SCL2)2 AND TRANS-BIS (DICHLORSULFAN) PALLADIUM(II) CHLORIDE PDCL2(SCL2)2
PAULUS, M
THIELE, G
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 588 (09): : 69 - 76
[40] COORDINATION, OLIGOMERIZATION AND TRANSFER HYDROGENATION OF ACETYLENES BY SOME RUTHENIUM AND OSMIUM CARBOXYLATES - CRYSTAL AND MOLECULAR-STRUCTURES OF BIS(TRIFLUOROACETATO)CARBONYL-(METHANOL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) AND (1,4-DIPHENYLBUT-1-EN-3-YN-2-YL)TRIFLUOROACETATO-(CARBONYL)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)R
DOBSON, A
MOORE, DS
ROBINSON, SD
HURSTHOUSE, MB
NEW, L
POLYHEDRON, 1985, 4 (06) : 1119 - 1130

← 1 2 3 4 5 →