SINGLE-ELECTRON TRANSFER REGIOSELECTIVE PHOTOCATALYTIC SYNTHESIS OF 2-CYANO-1,2,5,6-TETRAHYDROPYRIDINES

被引:0
|
作者
FERROUD, C [1 ]
DEAMORIM, EIC [1 ]
DALLERY, L [1 ]
SANTAMARIA, J [1 ]
机构
[1] ECOLE SUPER PHYS & CHIM IND VILLE PARIS,CNAM & CNRS,UNITE CHIM ORGAN,10 RUE VAUQUELIN,F-75231 PARIS 05,FRANCE
来源
SYNTHESIS-STUTTGART | 1994年 / 03期
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A mild and regioselective single electron transfer (SET) photocatalytic general synthesis of 2-cyano-1,2,5,6-tetrahydropyridines from 1,2,5,6-tetrahydropyridines is described. Cyanotrimethylsilane is used as cyanating agent in the presence of tetraphenylporphyrin (TPP) as photosensitizer.
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页码:291 / 294
页数:4
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