5-COORDINATE HYDRIDO OLEFIN PLATINUM(II) COMPLEXES

被引：10

作者：

DEFELICE, V

FERRARA, ML

PANUNZI, A

RUFFO, F

机构：

[1] NAPLES UNIV,DIPARTIMENTO CHIM,VIA MEZZOCANNONE 4,I-80134 NAPLES,ITALY

[2] UNIV MOLISE,FAC AGR,I-86100 CAMPOBASSO,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 439卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)80238-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable five-coordinate hydrido/olefin complexes of general formula [Pt(2,9-Me2-1,10-phenanthroline)H(Cl)(olefin)] have been synthesized in high yield through oxidative addition of HCl to [Pt(2,9-Me2-1,10-phenanthroline)(olefin)] precursors. Relevant spectroscopic features and some preliminary results concerning the reactivity of the new compounds are also reported.

引用

页码：C49 / C51

页数：3

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