EFFECT OF THE CARBOXYLATE GROUP DISTRIBUTION ON POTENTIOMETRIC TITRATION OF ACRYLAMIDE-ACRYLIC ACID COPOLYMERS

被引：15
|
作者：
TRUONG, ND [1 ]
MEDJAHDI, G [1 ]
SARAZIN, D [1 ]
FRANCOIS, J [1 ]
机构：
[1] INST CHARLES SADRON,CTR RECH MACROMOLEC,6 RUE BOUSSINGAULT,F-67083 STRASBOURG,FRANCE
来源：
POLYMER BULLETIN | 1990年 / 24卷 / 01期
关键词：
D O I：
10.1007/BF00298328
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
the potentiometric behavior of acrylamide-acrylic acid copolymers is discussed as a function of their method of preparation: base hydrolysis of polyacrylamide or radical copolymerization. The values of pK0 (the intrinsic pK at zero degree of ionization) and the variations of pKa versus the ionization degree are found to depend on the origin of the polymers and such differences are qualitatively attributed to significant discrepancies in the carboxylate group distribution. © 1990 Springer-Verlag.
引用
收藏
页码：101 / 106
页数：6
相关论文
共 50 条
  • [31] NONAQUEOUS POTENTIOMETRIC TITRATION OF COPOLYMERS CONTAINING ITACONIC ACID OR ITS MONOESTERS
    VACLAVOVA, E
    KELEMEN, P
    HRIVIK, A
    [J]. CHEMICAL PAPERS, 1994, 48 (03) : 203 - 205
  • [32] Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution
    Hisham Soliman Hassan
    Ahmed Mohamed El-Kamash
    Haneen Abdel-Salam Ibrahim
    [J]. Environmental Science and Pollution Research, 2019, 26 : 25641 - 25655
  • [33] Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution
    Hassan, Hisham Soliman
    El-Kamash, Ahmed Mohamed
    Ibrahim, Haneen Abdel-Salam
    [J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2019, 26 (25) : 25641 - 25655
  • [34] Interaction of hydrogels of acrylic acid-acrylamide copolymers with cytochrome c
    Skobeleva, VB
    Zinchenko, AV
    Rogacheva, VB
    Zezin, AB
    Kabanov, VA
    [J]. POLYMER SCIENCE SERIES A, 2001, 43 (03) : 315 - 322
  • [35] Correction to: Evaluation of hydroxyapatite/poly(acrylamide-acrylic acid) for sorptive removal of strontium ions from aqueous solution
    Hisham Soliman Hassan
    Ahmed Mohamed El-Kamash
    Haneen Abdel-Salam Ibrahim
    [J]. Environmental Science and Pollution Research, 2020, 27 : 4553 - 4553
  • [36] Copolymers of Acrylonitrile and Acrylic Acid: Effect of Composition and Distribution of Chain Units on the Thermal Behavior of Copolymers
    R. V. Toms
    M. S. Balashov
    A. A. Shaova
    A. Yu. Gerval’d
    N. I. Prokopov
    A. V. Plutalova
    N. A. Grebenkina
    E. V. Chernikova
    [J]. Polymer Science, Series B, 2020, 62 : 102 - 115
  • [37] Copolymers of Acrylonitrile and Acrylic Acid: Effect of Composition and Distribution of Chain Units on the Thermal Behavior of Copolymers
    Toms, R. V.
    Balashov, M. S.
    Shaova, A. A.
    Gerval'd, A. Yu.
    Prokopov, N. I.
    Plutalova, A. V.
    Grebenkina, N. A.
    Chernikova, E. V.
    [J]. POLYMER SCIENCE SERIES B, 2020, 62 (02) : 102 - 115
  • [38] SEPARATION OF WATER ACETONE MIXTURE BY ACRYLAMIDE-ACRYLIC ACID COPOLYMER GEL - PREPARED IN PORES OF CERAMIC THIN MEMBRANE
    SAKOHARA, S
    SAKATA, T
    ASAEDA, M
    [J]. KOBUNSHI RONBUNSHU, 1989, 46 (10) : 635 - 638
  • [39] Homogeneous complex solution formed through interpolyelectrolyte complexation of poly(acrylamide-acrylic acid) with poly(acrylamide-dimethyldiallylammonium chloride) in aqueous media
    Dan, Y
    Wang, Q
    [J]. POLYMER INTERNATIONAL, 2000, 49 (06) : 551 - 560
  • [40] SLOW REVERSIBLE COLLAPSE OF GELS BASED ON COPOLYMERS OF ACRYLAMIDE AND ACRYLIC-ACID
    BUDTOVA, TV
    BELNIKEVICH, NG
    BUYANOV, AL
    REVELSKAYA, LG
    PETROPAVLOVSKY, GA
    FRENKEL, SY
    [J]. ACTA POLYMERICA, 1991, 42 (04) : 160 - 164
12345