CATALYSIS OF ALLYLIC SUBSTITUTIONS BY PD COMPLEXES OF OXAZOLINES CONTAINING AN ADDITIONAL P, S, OR SE CENTER - X-RAY CRYSTAL-STRUCTURES AND SOLUTION STRUCTURES OF CHIRAL PI-ALLYL PALLADIUM COMPLEXES OF PHOSPHINOARYLOXAZOLINES

被引：372

作者：

SPRINZ, J

KIEFER, M

HELMCHEN, G

HUTTNER, G

WALTER, O

ZSOLNAI, L

REGGELIN, M

机构：

[1] UNIV HEIDELBERG,INST ORGAN CHEM,D-69120 HEIDELBERG,GERMANY

[2] UNIV FRANKFURT,INST ORGAN CHEM,D-60439 FRANKFURT,GERMANY

[3] UNIV HEIDELBERG,INST ANORGAN CHEM,D-69120 HEIDELBERG,GERMANY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)76748-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic alkylations with Pd complexes of chiral oxazolines with an additional donor P, S, or Se center are reported. Crystal and solution structures of palladium pi-allyl complexes of phosphinoaryloxazolines were determined by X-ray crystallography and cross relaxation experiments, respectively. From the results conclusions concerning the steric course of allylic substitutions are drawn.

引用

页码：1523 / 1526

页数：4

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