STRUCTURAL STUDY ON QUASI-PHOSPHONIUM SALTS CONTAINING PHOSPHORUS OXYGEN, PHOSPHORUS-NITROGEN AND PHOSPHORUS SULFUR BONDS

被引：17

作者：

IMRIE, C

MODRO, TA

VANROOYEN, PHG

WAGENER, CCP

WALLACE, K

HUDSON, HR

MCPARTLIN, M

NASIRUN, JB

POWROZNYK, L

机构：

[1] UNIV PRETORIA,DEPT CHEM,CT HETEROATOM CHEM,PRETORIA 0002,SOUTH AFRICA

[2] UNIV N LONDON,SCH APPL CHEM,LONDON N7 8DB,ENGLAND

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1995年 / 8卷 / 01期

关键词：

D O I：

10.1002/poc.610080109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The crystal and molecular structures of six quasi-phosphonium salts containing phosphorus-heteroatom (heteroatom = oxygen, sulphur or nitrogen) bonds were determined. Comparison of the molecular parameters obtained with those available for reference structures demonstrated that the 'double bond' character for the P+ - Y bond decreases in the order Y = N much greater than O > S.

引用

页码：41 / 46

页数：6

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