THE DOUBLE CARBONYLATION OF DIIODOMETHANE CATALYZED BY RHODIUM COMPLEXES

被引：13
|
作者：
WESTON, WS [1 ]
GASH, RC [1 ]
COLEHAMILTON, DJ [1 ]
机构：
[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 06期
关键词：
D O I：
10.1039/c39940000745
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In alcohols, ROH, in the presence of [Rh2(OAC)4], and optionally also in the presence of a tertiary phosphorus ligand PR'3, CH2I2 reacts with CO to give CH2(CO2R)2, CH2(OR)2 and RI.
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收藏
页码：745 / 746
页数：2
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