THE PREPARATION AND ELECTROCHEMISTRY OF TECHNETIUM AND RHENIUM COMPLEXES OF 2-(DIPHENYLPHOSPHINO)BENZENETHIOL - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RE(2-PH2PC6H4S)3] AND [TC(2-PH2PC6H4S)3]

被引：40
|
作者：
DILWORTH, JR
HUTSON, AJ
MORTON, S
HARMAN, M
HURSTHOUSE, MB
ZUBIETA, J
ARCHER, CM
KELLY, JD
机构：
[1] UNIV WALES COLL CARDIFF,COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES
[2] SYRACUSE UNIV,DEPT CHEM,NEW YORK,NY 13244
[3] AMERSHAM INT PLC,AMERSHAM HP7 9LL,BUCKS,ENGLAND
来源：
POLYHEDRON | 1992年 / 11卷 / 17期
关键词：
D O I：
10.1016/S0277-5387(00)83689-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of a variety of rhenium(III) or (V) precursors with the bidentate (1 -) mixed phosphino-thiol ligand 2-(diphenylphosphino)benzenethiol (DPPBTH) in mildly alkaline methanol leads to the formation of the 16-electron complex [Re(DPPBT)3] (I). With technetium [Tc(DPPBT)3] (II), [TcOCl(DPPBT)2] (III) or [TcN(DPPBT)2] (IV) may be obtained depending on the conditions and starting material. The X-ray crystal and molecular structures of I and II show very similar distortions from ideal geometry due to intraligand interactions. The complexes have been further studied by cyclic voltammetry and UV-vis spectroscopy.
引用
收藏
页码：2151 / 2155
页数：5
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