DIHYDROINDOL-7(6H)-ONES AND 6,7-DIHYDROPYRROLO[2,3-C]AZEPINE-4,8(1H,5H)-DIONE

被引：12

作者：

KASUM, B ^{[1
]}

PRAGER, RH ^{[1
]}

TSOPELAS, C ^{[1
]}

机构：

[1] FLINDERS UNIV S AUSTRALIA,SCH PHYS SCI,BEDFORD PK,SA 5042,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 02期

关键词：

D O I：

10.1071/CH9900355

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Methylcyclohexenones may be converted into dihydroindol-7(6H)-ones by conversion of the epoxide into the 2-benzylamino-3-methylcyclohexenone, which reacts with dimethyl-formamide dimethyl acetal to give N-benzyldihydroindol-7(6H)-ones. The limitations of the process are discussed, as is the failure to convert the dihydroindol-7(6H)-ones into dihydropyrroloazepinediones by Beckmann or Schmidt rearrangements. An example of the latter compounds was made by a simple procedure from pyrrolecarboxylic acid. © 1990 ASEG.

引用

页码：355 / 365

页数：11

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