REDUCTION OF CU(111)/O AT 298-K WITH CO

被引：2
|
作者：
VANKOOTEN, WEJ [1 ]
VANNISPEN, JPC [1 ]
GIJZEMAN, OLJ [1 ]
GEUS, JW [1 ]
机构：
[1] UNIV UTRECHT,DEBYE INST,DIV SURFACE SCI,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS
来源：
SURFACE SCIENCE | 1994年 / 315卷 / 03期
关键词：
D O I：
10.1016/0039-6028(94)90126-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reduction of Cu(111)/O with CO appeared to be possible at 298 K with CO pressures in the 10(-2) Pa range. The apparent activation energy at low temperatures is 14.6 kJ mol-1 which is significantly lower than at temperatures above 475 K. The oxidation temperature has a marked influence on the subsequent reduction at 298 K. For partially oxidised surfaces the oxygen distribution has influence on the reduction kinetics as well.
引用
收藏
页码：219 / 226
页数：8
相关论文
共 50 条
  • [21] CRYSTAL-STRUCTURE OF H2S2O7 AT 298-K
    HONLE, W
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1991, 196 (1-4): : 279 - 288
  • [22] RATE COEFFICIENTS FOR CS REACTIONS WITH O-2, O-3 AND NO2 AT 298-K
    BLACK, G
    JUSINSKI, LE
    SLANGER, TG
    CHEMICAL PHYSICS LETTERS, 1983, 102 (01) : 64 - 68
  • [23] RATE COEFFICIENTS AT 298-K FOR SO REACTIONS WITH O-2, O-3, AND NO2
    BLACK, G
    SHARPLESS, RL
    SLANGER, TG
    CHEMICAL PHYSICS LETTERS, 1982, 90 (01) : 55 - 58
  • [24] ENTHALPY OF SOLUTION OF FERROUS-CHLORIDE IN WATER AT 298-K
    CERUTTI, PJ
    HEPLER, LG
    THERMOCHIMICA ACTA, 1977, 20 (03) : 309 - 314
  • [25] ABSOLUTE RATE CONSTANTS FOR SILYLENE REACTIONS WITH HYDROCARBONS AT 298-K
    CHU, JO
    BEACH, DB
    JASINSKI, JM
    JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (20): : 5340 - 5343
  • [26] DEALLOYING AT ELEVATED-TEMPERATURES AND AT 298-K - SIMILARITIES AND DIFFERENCES
    PICKERING, HW
    KIM, YS
    CORROSION SCIENCE, 1982, 22 (07) : 621 - 635
  • [27] CALORIMETRY OF TETRAHEDRIC OXOANIONS IN AQUEOUS-SOLUTION AT 298-K
    DRAKIN, SI
    POPOVA, OV
    ZHURNAL FIZICHESKOI KHIMII, 1993, 67 (03): : 606 - 608
  • [28] PROTON-TRANSFER REACTIONS OF HCO+ AT 298-K
    TANNER, SD
    MACKAY, GI
    HOPKINSON, AC
    BOHME, DK
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1979, 29 (02) : 153 - 169
  • [29] HEAT-CAPACITIES OF LIQUID KETONES AND ALDEHYDES AT 298-K
    FUCHS, R
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1980, 58 (22): : 2305 - 2306
  • [30] ESTIMATIONS OF THE HEATS OF VAPORIZATION OF SIMPLE HYDROCARBON DERIVATIVES AT 298-K
    CHICKOS, JS
    HESSE, DG
    LIEBMAN, JF
    PANSHIN, SY
    JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15): : 3424 - 3429
12345