COMPLEXES WITH HYDROCARBON BRIDGES .23. HETEROBIMETALLIC COMPLEXES WITH FERROCENYL AND (PH3P)(OC)(CP)FEC(O)CH2 GROUPS - SYNTHESIS AND STRUCTURE OF (ETA-5-C5H5)FE[ETA-5-C5H4C(O)RE(CO)5], (PPH3)(OC)(CP)FEC(O)CH2((ETA-6-C7H7)M(CO)3 AND [ETA-5-C5H4C(O)(CH3]FE[ETA-5-C5H4C(O)CH2(ETA-6-C7H7)M(CO)3] (M = CR, MO)

被引：18

作者：

BREIMAIR, J ^{[1
]}

WIESER, M ^{[1
]}

WAGNER, B ^{[1
]}

POLBORN, K ^{[1
]}

BECK, W ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 421卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)86431-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the organometallic enolates [eta-5-C5H4C(O)CH3]Fe(eta-5-C5H4C(O)CH2]- and [Cp(Ph3P)(OC)FeC(O)CH2]- with [(OC)3M(C7H7)]+ (M = Cr, Mo) proceed with C-C coupling and give the complexes (eta-5-C5H4C(O)CH3)Fe[eta-5-C5H4C(O)CH2(eta-6-C7H7)M(CO)3 (1a,b) and Cp(Ph3P)(OC)FeC(O)CH2(eta-6-C7H7)M(CO)3 (2a,b), respectively. CpFe[eta-5-C5H4C(O)Re(CO)5] (3) is obtained from CpFe[eta-5-C5H4C(O)Cl] and Re(CO)5-. The structures of 1b and 3 have been determined by X-ray diffraction.

引用

页码：55 / 64

页数：10

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