THERMODYNAMIC STABILIZATION OF NICKEL(III) BY AMIDE-CONTAINING LIGANDS - ELECTROCHEMICAL INVESTIGATION OF COMPLEXES WITH 13-MEMBERED AND 14-MEMBERED DIOXOTETRAAZAMACROCYCLES

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作者
GAVRISH, SP [1 ]
LAMPEKA, YD [1 ]
机构
[1] LV PISARZHEVSKII INST PHYS CHEM,KIEV,UKRAINE
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It was shown that accepted in literature Ni(III)L/Ni(II)L redox-potentials of nickel complexes with 13- and 14-membered dioxotetraazamacrocycles refer to redox transition of metal ion in complexes with containing derivatives of starting ligands, the actual E1/2 values of given compounds being considerably lower.
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页码:343 / 349
页数:7
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