SUBSTITUENT EFFECTS IN CLUSTERS .5. UV-PHOTOELECTRON SPECTROSCOPIC AND QUANTUM-CHEMICAL ANALYSES OF H3OS3(CO)9BCO, H2OS3(CO)9CCO, AND RELATED CLUSTERS

被引：27

作者：

BARRETO, RD

FEHLNER, TP

HSU, LY

JAN, DY

SHORE, SG

机构：

[1] UNIV NOTRE DAME,DEPT CHEM,NOTRE DAME,IN 46556

[2] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

INORGANIC CHEMISTRY | 1986年 / 25卷 / 20期

关键词：

D O I：

10.1021/ic00240a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：3572 / 3581

页数：10

共 50 条

[41] Reactions of diacetylene ligands with trinuclear clusters.: 3.: Cyclization of diynes with β-amino moieties on the metal core of [H2Os3(CO)10]
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[42] DOUBLE METALATION AND IRON OSMIUM BONDING INVOLVING FERROCENYL MOIETIES ON CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURES OF H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PPRI2)] AND H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PFCET)]
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[43] FERROCYNE AND FERRODICYNE - PREPARATION AND STRUCTURES OF OS3(CO)9[MU-3-(C5H3)FE(C5H5)][MU-3-P(C5H4)FE(C5H5)], OS3(H)2(CO)8(PPRI2C5H2)FE(C5H2PPRI2)OS3(H)2(CO)8, AND OS3(CO)9[MU-3-C6H4][MU-3-P(C5H4)FE(C5H5)]
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[44] ISOMERIZATION AND FLUXIONAL BEHAVIOR OF THE TETRAHEDRO-TRIOSMIUM PLATINUM CLUSTERS OS3PT(MU-H)2(CO)9(PT-PCY3)(OS-PR3) - X-RAY CRYSTAL-STRUCTURE OF OS3PT(MU-H)2(CO)9(PT-PCY3)(OS-PPH3)
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[45] ON THE INTERFACE OF METAL METAL MULTIPLE BOND COMPOUNDS AND ORGANOMETALLIC CLUSTERS - SYNTHESIS AND STRUCTURE OF MO2(MU-[(CO)9CO3(MU-3-CCO2)])4[(CO)9CO3(MU-3-CCO2H)]2 AND RELATED-COMPOUNDS
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[46] Reactions of the face-capped benzothiazolate-substituted clusters Os3(CO)9(μ3,η2-C7H3NSR)(μ-H) (R = H, Me) with PPh3: Kinetic formation of Os3(CO)9(PPh3)(μ,η2-C7H3NSR)(μ-H) and thermally induced ligand isomerization
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[47] Sequential H-migration reactions in the formation of [Os-3(mu(2)-H)(mu(2)-PHMe)(CO)(10)] and [Os-3(mu(2)-H)(2)(mu(3)-PMe)(CO)(9)] during the reaction between the phosphinidene complex [W(PMe)(CO)(5)] and [Os-3(mu(2)-H)(2)(CO)(10)]
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[48] Reactions of unsaturated quinoline triosmium clusters [Os3(CO)9(μ3-η2-C9H5(4-R)N)(μ-H)] (R = Me or H) with tetramethylthiourea:: X-ray structures of [Os3(CO)8(μ-η2-C9H5(4-Me)N) (η2-SC(NMe2NCH2Me)(μ-H)2] and [Os3(CO)9 (μ-η2-C9H6N)(η1-SC(NMe2)2)(μ-H)]
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[49] Phosphine derivatives of the 4-methylquinoline triosmium cluster [(μ-H)Os3(CO)10{μ-1,2-η2-C9H5(CH3)N}]:: crystal structures of two isomeric compounds [(μ-H)Os3(CO)9{μ-1,2-η2-C9H5(CH3)N}(PPh3)] and [(μ-H)Os3(CO)9{μ-1,2-η2-C9H5(CH3)N}{P(OMe)3}]
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[50] Reactions of Unsaturated Quinoline Triosmium Clusters [Os3(CO)9(μ3-η2-C9H5(4-R)N)(μ-H)] (R=Me or H) with Tetramethylthiourea: X-ray Structures of [Os3(CO)8(μ-η2-C9H5(4-Me)N)(η2-SC(NMe2NCH2Me)(μ-H)2] and [Os3(CO)9(μ-η2-C9H6N)(η1-SC(NMe2)2)(μ-H)]
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