HYDRODECHLORINATION OF CHLOROAROMATICS - THE USE OF A BIFUNCTIONAL HOMOGENOUS RHODIUM CATALYST FOR THE CONVERSION OF CHLOROAROMATICS INTO SATURATED-HYDROCARBONS

被引：40

作者：

FERRUGHELLI, DT ^{[1
]}

HORVATH, IT ^{[1
]}

机构：

[1] EXXON RES & ENGN CO,CORP RES LABS,ANNANDALE,NJ 08801

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic conversion of chloroaromatics into the corresponding saturated hydrocarbons is catalysed by a bifunctional homogeneous rhodium catalyst system generated from [(C5Me5)RhCl2]2 in the presence of an excess of NEt3 under 600 psi H-2 at 75-degrees-C (1 psi almost-equal-to 6.894757 x 10(3) Pa).

引用

页码：806 / 807

页数：2

共 33 条

[31] ACTIVATION OF SATURATED-HYDROCARBONS BY TRANSITION-METAL COMPLEXES IN SOLUTION .3. USE OF PHOTOELECTRON SPECTRA OF HALOGEN-SUBSTITUTED HYDROCARBONS AND HYDROCARBONS CONTAINING QUATERNARY CARBON-ATOMS TO INTERPRET NATURE OF PLATINUM(II)-CATALYSED HYDROGEN-DEUTERIUM EXCHANG
HODGES, RJ
WEBSTER, DE
WELLS, PB
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (23): : 2577 - 2583
[32] ACTIVATION OF C-H BONDS IN SATURATED-HYDROCARBONS - THE FORMATION OF BIS-(TRIPHENYLPHOSPHINE) (ETA-ALKADIENE)RHENIUM TRIHYDRIDES FROM N-ALKANES, AND THEIR SELECTIVE CONVERSION INTO THE CORRESPONDING 1-ALKENES
BAUDRY, D
EPHRITIKHINE, M
FELKIN, H
ZAKRZEWSKI, J
TETRAHEDRON LETTERS, 1984, 25 (12) : 1283 - 1286
[33] Syngas conversion into light hydrocarbons over bifunctional catalyst: Effect of the density of contact between Cu-ZnO-Al2O3 and SAPO-34
L'hospital, Valentin
Coudercy, Christophe
Pinard, Ludovic
Rousseau, Julie
Loridant, Stephane
Le Valant, Anthony
APPLIED CATALYSIS A-GENERAL, 2022, 643

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