DIODE-LASER JET SPECTROSCOPY OF 1,4-DIOXANE

被引：8
|
作者：
BROWN, PR [1 ]
DAVIES, PB [1 ]
HANSFORD, GM [1 ]
MARTIN, NA [1 ]
机构：
[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 158卷 / 02期
关键词：
D O I：
10.1006/jmsp.1993.1090
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
High resolution infrared absorption spectra of the 1510 band of 1,4-dioxane (C4H8O2) have been recorded in a supersonic jet with diode lasers. Analysis of 136 P-, Q-, and R-branch lines of this B-type band yielded accurate rotational parameters for both ground and upper states. The Quartic distortion constants were not determinable from the data. The advantage of jet-cooling in rendering the spectrum amenable to analysis is clearly demonstrated. © 1993 Academic Press, Inc.
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页码：468 / 478
页数：11
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