INFLUENCE OF N-HEXADECYL-N,N,N-TRIMETHYLAMMONIUM NITRATE ON THE DEHYDROBROMINATION REACTION OF 2-PHENYLETHYL DERIVATIVES

被引：7

作者：

WILK, KA

机构：

[1] Institute of Organic and Polymer Technology, Technical University of Wroclaw, Wroclaw

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1990年 / 22卷 / 03期

关键词：

D O I：

10.1002/kin.550220305

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The basis dehydrobromination of p‐substituted 2‐phenylethyl bromides promoted by hydroxide ion has been studied in micelles of N‐hexadecyl‐N,N,N‐trimethylammonium nitrate (CTANO3). The pseudophase ion exchange model can be adapted to explain the kinetic results at low hydroxide ion concentration, i.e., less than 0.075 M of NaOH. At high hydroxide ion concentration in solution the applied model does not describe the kinetic results unless the empirical variations are applied for the mol ratio of reactive ion to micellar head group (β) and the binding constant of the organic reagent to the micelle (Ks). Copyright © 1990 John Wiley & Sons, Inc.

引用

页码：253 / 259

页数：7

共 50 条

[21] Synthesis, structure, and characteristics of ultra-high-molecular-weight: Poly-N-methacryloyloxyethyl-N,N,N-trimethylammonium methyl sulfate
Molotkov, V.A.
Kurlyankina, V.I.
Klenin, S.I.
Matveeva, N.A.
Shishkina, G.V.
Kipper, A.I.
Khlebosolova, E.N.
Ostrovskaya, L.D.
Rumyantseva, N.V.
Valueva, S.V.
[J]. 1600, Maik Nauka-Interperiodica Publishing (74):
[22] Synthesis, Structure, and Characteristics of Ultra-High-Molecular-Weight Poly-N-methacryloyloxyethyl-N,N,N-Trimethylammonium Methyl Sulfate
V. A. Molotkov
V. I. Kurlyankina
S. I. Klenin
N. A. Matveeva
G. V. Shishkina
A. I. Kipper
E. N. Khlebosolova
L. D. Ostrovskaya
N. V. Rumyantseva
S. V. Valueva
[J]. Russian Journal of Applied Chemistry, 2001, 74 : 1002 - 1006
[23] Micellar size, shape and counterion binding of N-(1,1-Dihydroperfluoroalkyl)-N,N,N-trimethylammonium chloride in aqueous solutions
Keisuke Matsuoka
Aki Yonekawa
Mariko Ishii
Chikako Honda
Kazutoyo Endo
Yoshikiyo Moroi
Yutaka Abe
Takamitsu Tamura
[J]. Colloid and Polymer Science, 2006, 285 : 323 - 330
[24] Synthesis, structure, and characteristics of ultra-high-molecular-weight poly-N-methacryloyloxyethyl-N,N,N-trimethylammonium methyl sulfate
Molotkov, VA
Kurlyankina, VI
Klenin, SI
Matveeva, NA
Shishkina, GV
Kipper, AI
Khlebosolova, EN
Ostrovskaya, LD
Rumyantseva, NV
Valueva, SV
[J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2001, 74 (06) : 1002 - 1006
[25] Effect of N-cetyl-N,N,N-trimethylammonium bromide and orthophenylenediamine on the corrosion inhibition of carbon steel in 1 mol/L HCl
Babu, B. Ramesh
Parande, A. K.
Ramasamy, P. L.
[J]. CANADIAN JOURNAL OF CHEMISTRY, 2006, 84 (12) : 1658 - 1666
[26] CRYSTAL-STRUCTURE OF INCLUSION COMPLEX OF DI(2-PHENYLETHYL)-N,N'-BIS(1-NAPHTHYL)MALONAMIDE, DI(2-PHENYLETHYL)-N-(1-NAPHTHYL)CARBAMOYLMETHANE AND BENZENE
GOTO, M
HIRATANI, K
HONDA, K
KOJIMA, I
[J]. ANALYTICAL SCIENCES, 1994, 10 (06) : 973 - 975
[27] INFLUENCE OF NORMAL-BUTYL AND NORMAL-HEXYL ALCOHOLS IN THE DEHYDROHALOGENATION OF DDT IN CATIONIC MICELLES OF N-CETYL-N,N,N-TRIMETHYLAMMONIUM BROMIDE, CHLORIDE, AND HYDROXIDE
OTERO, C
RODENAS, E
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (22): : 5771 - 5775
[28] EFFECT OF N-ALKYL-N,N,N-TRIMETHYLAMMONIUM IONS ON PHOSPHATIDYLCHOLINE MODEL MEMBRANE-STRUCTURE AS STUDIED BY P-31-NMR
BALGAVY, P
GAWRISCH, K
FRISCHLEDER, H
[J]. BIOCHIMICA ET BIOPHYSICA ACTA, 1984, 772 (01) : 58 - 64
[29] Improvement of washing properties of liquid laundry detergents by modification with N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate sulfobetaine
Kalak, Tomasz
Gasior, Krzysztof
Wieczorek, Daria
Cierpiszewski, Ryszard
[J]. TEXTILE RESEARCH JOURNAL, 2021, 91 (1-2) : 115 - 129
[30] THE LATERAL ORDER OF DIPALMITOYLPHOSPHATIDYLCHOLINE MODEL MEMBRANES IN THE PRESENCE OF N-ALKYL-N,N,N-TRIMETHYLAMMONIUM IONS AS STUDIED BY RAMAN-SPECTROSCOPY .3.
CIRAK, J
BALGAVY, P
DEVINSKY, F
[J]. GENERAL PHYSIOLOGY AND BIOPHYSICS, 1988, 7 (06) : 633 - 642

← 1 2 3 4 5 →