GLYCINE C-60 ADDUCT AND ITS RARE-EARTH COMPLEXES

被引：18
|
作者：
ZHOU, DJ [1 ]
GAN, LB [1 ]
XU, LB [1 ]
LUO, CP [1 ]
HUANG, CH [1 ]
机构：
[1] BEIJING UNIV,DEPT CHEM,STATE KEY LAB RARE EARTH MAT CHEM & APPLICAT,BEIJING 100871,PEOPLES R CHINA
来源：
FULLERENE SCIENCE AND TECHNOLOGY | 1995年 / 3卷 / 02期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1080/153638X9508543775
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Glycine sodium salt reacts with C-60 to give a water soluble derivative 1, acidification of which produces a less soluble product 2. When compound 2 is treated with Ln(ClO4)(3) (Ln=La,Y) in several different molar ratios, insoluble rare earth complexes: C-60(Gly)(x)Ln(x/3)(OH)(y)(H2O)(z) (x=7-8,y=4-6,z=2-6) were obtained. These new compounds have been characterized by IR,TG-DTA and XPS spectra.
引用
收藏
页码：127 / 131
页数：5
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