PHENYLTHIO RADICAL CATALYZED REARRANGEMENT OF ACETOXYALKENYL EPOXIDES TO ACETOXYALKENYL CYCLOPENTANOLS

被引：41
|
作者：
RAWAL, VH
KRISHNAMURTHY, V
机构：
[1] Department of Chemistry, The Ohio State University Columbus
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期
关键词：
PHENYLTHIO RADICAL; ENOLACETATE; RADICAL CATALYZED CYCLIZATION; EPOXIDE FRAGMENTATION;
D O I：
10.1016/S0040-4039(00)92657-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Exposure of cyclic acetoxyalkenyl epoxides to a catalytic amount of PhS. initiates a tandem radical induced epoxide fragmentation-H. abstraction-cyclization process that results in a net isomerization to bicyclic enolacetates.
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页码：3439 / 3442
页数：4
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