REACTION OF CHIRAL CYCLOPROPYL HALIDES WITH SMI2

被引：29
|
作者：
WALBORSKY, HM
TOPOLSKI, M
机构：
[1] Dittmer Laboratories of Chemistry, Florida State University, Tallahassee
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 01期
关键词：
D O I：
10.1021/jo00027a064
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reductions of (S)-(+)-1-bromo-1-methyl-2,2-diphenylcyclopropane (7), (S)-(+)-1-bromo-1-(methoxy-methyl)-2,2-diphenylcyclopropane (19), and (R)-(-)-1-fluoro-1-iodo-2,2-diphenylcyclopropane (11) with samarium(II) iodide is reported. Evidence for a samarium(III) intermediate in the reaction is presented.
引用
收藏
页码：370 / 373
页数：4
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