WEAK H-BONDING BY 2ND-ROW (PH3, H2S) AND 3RD-ROW (ASH3, H2SE) HYDRIDES

被引：66
|
作者：
SENNIKOV, PG
机构：
[1] Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, GSP-75, Nizhny Novgorod, 603600
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 19期
关键词：
D O I：
10.1021/j100070a006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The properties of weak hydrogen-bonded complexes composed of simple hydride molecules of the elements of the second and third rows (PH3, AsH3, H2S, and H2Se) are reviewed. The results of theoretical methods (ab initio calculations) and experimental analyses (molecular beam microwave spectroscopy, IR matrix isolation spectroscopy, and IR spectroscopy in conventional and cryosolutions) are used. The spectroscopic, structural, and energetic features of hydride-water and hydride-ethanol H-complexes measured directly in hydrides are discussed.
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页码：4973 / 4981
页数：9
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