Synthesis of the first thorium-containing nitride perovskite, TaThN3

被引:49
|
作者
Brese, NE [1 ]
DiSalvo, FJ [1 ]
机构
[1] CORNELL UNIV,BAKER LAB,DEPT CHEM,ITHACA,NY 14853
关键词
D O I
10.1006/jssc.1995.1423
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
TaThN3 can be prepared from a reaction of Ta2Th2O9 and Ca3N2 at 1100-1500 degrees C or from a reaction of Ta3N5 and Th3N4 at 1400 degrees C. This black polycrystalline material crystallizes in the perovskite structure type with a = 4.020(6) Angstrom. (C) 1995 Academic Press, Inc.
引用
收藏
页码:378 / 380
页数:3
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