HARD/SOFT INTERACTIONS IN EARLY TRANSITION-METAL THIOETHER MACROCYCLIC CHEMISTRY - SYNTHESIS AND SINGLE-CRYSTAL STRUCTURE OF CIS-[CRCL2([14]ANES(4))PF6 ([14]ANES(4)=1,4,8,11-TETRATHIACYCLOTETRADECANE)

被引：24

作者：

CHAMPNESS, NR

JACOB, SR

REID, G

FRAMPTON, CS

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

[2] ROCHE PROD LTD,WELWYN GARDEN CIT AL7 3AY,HERTS,ENGLAND

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

10.1021/ic00105a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [CrCl2([14]aneS(4))]PF6; a rare example of thioether coordination to Cr(III), has been isolated. The X-ray structure of [CrCl2([14]aneS(4))]PF6 shows the Crm ion coordinated to all four thioether donors of a folded [14]aneS(4) ligand with cis-dichloro ligands completing the distorted octahedral stereochemistry: Cr-Cl = 2.295(1) Angstrom, Cr-S = 2.393(1), 2.407(2) Angstrom.

引用

页码：396 / 398

页数：3

共 32 条

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BLAKE, AJ
GOULD, RO
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[22] REACTIONS OF 1,4,7-TRITHIACYCLONANE, [9]ANES3, WITH EARLY TRANSITION-METAL HALIDES - SYNTHESIS AND X-RAY STRUCTURE OF (FE([9]ANES3)2)[SB2CL8]
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TRANSITION METAL CHEMISTRY, 1994, 19 (02) : 187 - 190
[23] ON THE TRANSPORT AND SELECTIVE COMPLEXATION OF SILVER(I) BY MIXED THIOETHER-OXA CROWNS - THE SINGLE-CRYSTAL X-RAY STRUCTURES OF [AGN([15]ANES2O3)N](PF6)N AND [AG2([15]ANES2O3)3](PF6)2 ([15]ANES2O3 = 1,4,7-TRIOXA-10,13-DITHIACYCLOPENTADECANE)
BLAKE, AJ
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JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (15) : 1074 - 1076
[24] Mercury(II), silver(I) and gold(I) thioether crown chemistry:: Synthesis, electrochemistry and structures of [(HgBr2)2([24]aneS8)], [{Ag2([24]aneS8)(CF3SO3)2(MeCN)2}∞], [Ag2([28]aneS8)][NO3]2 and [Au2([28]aneS8)][PF6]2 ([24]aneS8 = 1,4,7,10,13,16,19,22-octathia-cyclotetracosane;: [28]aneS8 = 1,4,8,11,15,18,22,25-octathiacyclo-octacosane)
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (17): : 2931 - 2937
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BLAKE, AJ
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (12): : 3849 - 3856
[26] NICKEL THIOETHER CHEMISTRY - SYNTHESIS, STRUCTURES AND ELECTROCHEMISTRY OF 5-CO-ORDINATE NICKEL(II) COMPLEXES OF [9]ANES3 - CRYSTAL-STRUCTURES OF [NI([9]ANES3)-(DPPM)][PF6]2, [NI([9]ANES3)(DCPE)][PF6]2-CENTER-DOT-1.25MECN AND [NI([9]ANES3)(TDPME)][PF6]2 ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE, DPPM = PH2PCH2PPH2, DCPE = (C6H11)2-PC2H4P(C6H11)2, TDPME = CH3C(CH2PPH2)3)
BLAKE, AJ
GOULD, RO
HALCROW, MA
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (19): : 2909 - 2920
[27] SYNTHESIS AND CHARACTERIZATION OF THE THIOLATO RHENIUM(III) COMPLEXES CIS-[RE(SC6H4X-P)2(DMPE)2]PF6 AND TRANS-[RE(SC6H4X-P)2(DMPE)2]PF6, X = H, ME OR CL, DMPE = 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE - SINGLE-CRYSTAL STRUCTURAL-ANALYSIS OF CIS-[RE(SPH)2(DMPE)2]PF6
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TRANSITION METAL CHEMISTRY, 1993, 18 (03) : 335 - 341
[28] Coordination chemistry of substituted [1,2,4]triazolo[1,5-a]pyrimidines with first-row transition-metal ions: Synthesis, spectroscopy and single-crystal structure
Balkaran, Jeral M.
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van Bruchem, John
Verasdonck, Joeri
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Volbeda, Anne Geert
Mutikainen, Ilpo
Turpeinen, Urho
van Albada, Gerard A.
Gamez, Patrick
Haasnoot, Jaap G.
Reedijk, Jan
INORGANICA CHIMICA ACTA, 2009, 362 (03) : 861 - 868
[29] RHODIUM MACROCYCLIC COMPLEXES - THE SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURE OF [RH([18]ANEN2S4)](PF6)3.3H2O ([18]ANEN2S4=1,4,10,13-TETRATHIA-7,16-DIAZACYCLOOCTADECANE)
BLAKE, AJ
REID, G
SCHRODER, M
POLYHEDRON, 1990, 9 (24) : 2925 - 2929
[30] Coordination chemistry of 5,6,7-trimethyl-[1,2,4]triazolo[1,5-a]pyrimidine with first-row transition-metal salts: Synthesis, spectroscopy and single-crystal structures, with counter-anion dependence of the structures
Adriaanse, J. Huub
Askes, Sven H. C.
van Bree, Yorrick
van Oudheusden, Stefan
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Mutikainen, Ilpo
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van Albada, Gerard A.
Haasnoot, Jaap G.
Reedijk, Jan
POLYHEDRON, 2009, 28 (14) : 3143 - 3149

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