HARD/SOFT INTERACTIONS IN EARLY TRANSITION-METAL THIOETHER MACROCYCLIC CHEMISTRY - SYNTHESIS AND SINGLE-CRYSTAL STRUCTURE OF CIS-[CRCL2([14]ANES(4))PF6 ([14]ANES(4)=1,4,8,11-TETRATHIACYCLOTETRADECANE)

被引:24
|
作者
CHAMPNESS, NR
JACOB, SR
REID, G
FRAMPTON, CS
机构
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
[2] ROCHE PROD LTD,WELWYN GARDEN CIT AL7 3AY,HERTS,ENGLAND
关键词
D O I
10.1021/ic00105a061
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex [CrCl2([14]aneS(4))]PF6; a rare example of thioether coordination to Cr(III), has been isolated. The X-ray structure of [CrCl2([14]aneS(4))]PF6 shows the Crm ion coordinated to all four thioether donors of a folded [14]aneS(4) ligand with cis-dichloro ligands completing the distorted octahedral stereochemistry: Cr-Cl = 2.295(1) Angstrom, Cr-S = 2.393(1), 2.407(2) Angstrom.
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页码:396 / 398
页数:3
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