MOLECULAR AXIS ORIENTATION AND TRANSITIONAL PATH EFFECTS IN THE ROTATIONAL STRUCTURE OF MULTIPHOTON TRANSITIONS

被引:0
|
作者
MAINOS, C
机构
[1] Laboratoire de Physique des Lasers, Université Paris-Nord, Villetaneuse, 93430, Av. J. B. Clément
关键词
D O I
10.1080/00268979100101901
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The intensity distribution among the rotational branches in a multiphoton process is considered. It is shown that the excitation probability of a rotational line depends drastically on the transitional path involved as well as on the molecular axis orientation. Each transitional path derives a distinct rotational structure and the intensity distribution of the rotational branches in the excitation spectra reveals the dominant transitional path.
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页码:1241 / 1255
页数:15
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