Bis(1,10-phenanthroline-kappa N-2,N ')(sulfato-kappa O-2,O ')nickel(II) propane-1,2-diol monosolvate

被引：0
|
作者：
Zhong, Kai -Long [1 ]
Duan, Cheng-Xian [2 ]
机构：
[1] Nanjing Coll Chem Technol, Dept Appl Chem, Nanjing 210048, Jiangsu, Peoples R China
[2] AVIC Hefei Jianghang Aircraft Equipment Corp Ltd, Hefei 230051, Anhui, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813023027
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ni(SO4)(C12H8N2)(2)]center dot C3H8O2, the Ni-II atom exhibits a distorted octahedral coordination by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O '-bidentate sulfate group. A twofold rotation axis passes through the Ni and S atoms and the midpoint of the hydroxyl C-C bond of the propane-1,2-diol solvent molecule. The dihedral angle between the two chelating N2C2 groups is 85.61 (8)degrees. The [NiSO4(C10H8N2)(2)] and propane-1,2-diol units are held together by a pair of symmetry-related intermolecular O-H center dot center dot center dot O hydrogen bonds involving the uncoordinating O atoms of the sulfate ion. Due to symmetry, the solvent molecule is equally disordered over two positions.
引用
收藏
页码：M506 / +
页数：9
相关论文
共 50 条
  • [1] Bis(1,10-phenanthroline-kappa N-2,N ')(sulfato-kappa O-2,O ')cobalt(II) propane-1,2-diol monosolvate
    Zhong, Kai-Long
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M26 - +
  • [2] Bis(1,10-phenanthroline-kappa N-2,N ')(sulfato-kappa O-2,O ')nickel(II) butane-2,3-diol monosolvate
    Zhong, Kai-Long
    Ni, Chao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1519 - +
  • [3] Bis(1,10-phenanthroline-kappa N-2,N ')(sulfatoj-kappa O)zinc(II) propane-1,2-diol monosolvate
    Zhong, Kai-Long
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M561 - +
  • [4] Bis(1,10-phenanthroline-kappa N-2,N ')(sulfato-kappa O)copper(II) ethanol monosolvate
    Meundaeng, Natthaya
    Prior, Timothy J.
    Rujiwatra, Apinpus
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M568 - +
  • [5] Bis(1,10-phenanthroline-kappa N-2, N')(sulfatoO) copper(II) propane-1,3-diol monosolvate
    Zhong, Kai-Long
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1555 - +
  • [6] Bis(1,10-phenanthroline-kappa N-2,N ')(sulfato-O)copper(II) butane-2,3-diol monosolvate
    Zhong, Kai-Long
    Cao, Guo-Qing
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M40 - +
  • [7] Bis(cinnamato-kappa O)(1,10-phenanthroline-kappa N-2,N ')copper(II)
    Benslimane, Meriem
    Redjel, Yasmine Kheira
    Merazig, Hocine
    Daran, Jean-Claude
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M277 - +
  • [8] trans-Bis(nitrato-kappa O)bis(1,10-phenanthroline-kappa N-2,N ')manganese(II)
    Saphu, Watcharin
    Chanthee, Songwuit
    Chainok, Kittipong
    Harding, David J.
    Pakawatchai, Chaveng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1026 - +
  • [9] Chloridobis(1,10-phenanthroline-kappa N-2, N ')copper(II) chlorido(1,10-phenanthroline-kappa N-2, N ')(pyridine-2,6-dicarboxylato-kappa O-3(2),N,O-6)manganate(II) methanol monosolvate
    Buvailo, Halyna I.
    Rusanova, Julia A.
    Makhankova, Valeriya G.
    Kokozay, Vladimir N.
    Zubatyuk, Roman I.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M147 - +
  • [10] (Cyclobutane-1,1-dicarboxylato-kappa O-2,O ')-(1,10-phenanthroline-kappa N-2,N ')-platinum(II) dihydrate
    Starha, Pavel
    Travnicek, Zdenek
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M334 - +
12345