AN INVESTIGATION OF THE ELECTRONIC-STRUCTURE OF OSMIUM-TETROXIDE BY PHOTOELECTRON-SPECTROSCOPY WITH VARIABLE PHOTON ENERGY

被引：16

作者：

GREEN, JC ^{[1
]}

KALTSOYANNIS, N ^{[1
]}

SZE, KH ^{[1
]}

MACDONALD, MA ^{[1
]}

机构：

[1] SERC,DARESBURY LAB,WARRINGTON WA4 4AD,CHESHIRE,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 175卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)80125-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Relative partial photoionization cross sections and photoelectron branching ratios have been obtained for the valence bands of osmium tetroxide in the ionization energy range 12 to 18 eV. The photon energies used ranged between 24 and 100 eV. The ionization cross sections of the 2t2 and 2a1 orbitals show evidence of substantial metal character establishing strong Os-O sigma-bonding. Very little evidence is found for pi-bonding.

引用

页码：359 / 363

页数：5

共 50 条

[31] LOW-ENERGY PHOTOELECTRON-SPECTROSCOPY OF SOLIDS - ELECTRONIC-STRUCTURE OF CYANIDE, NITRITE, AND NITRATE IONS
CONSIDINE, M
CONNOR, JA
HILLIER, IH
INORGANIC CHEMISTRY, 1977, 16 (06) : 1392 - 1396
[32] ELECTRONIC-STRUCTURE OF C6BA STUDIED BY PHOTOELECTRON-SPECTROSCOPY
GUBLER, UM
GEISER, V
OELHAFEN, P
GUNTHERODT, HJ
EVERS, J
WEISS, A
SYNTHETIC METALS, 1983, 8 (1-2) : 141 - 145
[33] ELECTRONIC-STRUCTURE AND BONDING IN METAL-HYDRIDES, STUDIED WITH PHOTOELECTRON-SPECTROSCOPY
RIESTERER, T
ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1987, 66 (04): : 441 - 458
[34] VARIABLE PHOTON ENERGY PHOTOELECTRON SPECTROSCOPIC AND THEORETICAL INVESTIGATIONS OF THE ELECTRONIC-STRUCTURE OF TICL4
BURSTEN, BE
GREEN, JC
KALTSOYANNIS, N
MACDONALD, MA
SZE, KH
TSE, JS
INORGANIC CHEMISTRY, 1994, 33 (22) : 5086 - 5093
[35] Variable energy photoelectron spectroscopy: electronic structure and electronic relaxation
Solomon, EI
Basumallick, L
Chen, P
Kennepohl, P
COORDINATION CHEMISTRY REVIEWS, 2005, 249 (1-2) : 229 - 253
[36] INVESTIGATION OF ELECTRONIC-STRUCTURE OF TERNARY MOLYBDENUM SULFIDES BY MEANS OF X-RAY-EMISSION AND PHOTOELECTRON-SPECTROSCOPY
KURMAEV, EZ
YARMOSHENKO, YM
NYHOLM, R
MARTENSSON, N
JARLBORG, T
SOLID STATE COMMUNICATIONS, 1981, 37 (08) : 647 - 651
[37] VARIABLE PHOTON ENERGY PHOTOELECTRON-SPECTROSCOPY BF TRANSITION-METAL MOLECULES
GREEN, JC
ACCOUNTS OF CHEMICAL RESEARCH, 1994, 27 (05) : 131 - 137
[38] PHOTOELECTRON-SPECTROSCOPY OF SURFACES - ROLE OF PHOTON ENERGY
PLUMMER, EW
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 1 - 1
[39] STUDY OF ELECTRONIC-STRUCTURE OF SOME ALKYLTIN DERIVATIVES BY MEANS OF UV PHOTOELECTRON-SPECTROSCOPY
CAULETTI, C
FURLANI, C
PIANCASTELLI, MN
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 149 (03) : 289 - 295
[40] ELECTRONIC-STRUCTURE OF MGO STUDIED BY ANGLE-RESOLVED ULTRAVIOLET PHOTOELECTRON-SPECTROSCOPY
TJENG, LH
VOS, AR
SAWATZKY, GA
SURFACE SCIENCE, 1990, 235 (2-3) : 269 - 279

← 1 2 3 4 5 →