Tetrakis(2,6-dimethylpyridinium) dihydrogen decavanadate dihydrate

被引：5
|
作者：
Rakovsky, Erik [1 ]
Krivosudsky, Lukas [1 ]
机构：
[1] Comenius Univ, Fac Nat Sci, Dept Inorgan Chem, Mlynska Dolina CH2, SK-84215 Bratislava, Slovakia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536814011118
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound, (C7H10N)(4)[H2V10O28]-2H(2)O, was solved from a non-merohedrally twinned crystal (ratio of twin components similar to 0.6:0.4). The asymmetric unit consists of one-half decavanadate anion (the other half completed by inversion symmetry), two 2,6-dimethylpyridinium cations and one water molecule of crystallization. In the crystal, the components are connected by strong N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds, forming a supramolecular chain along the b-axis direction. There are weak C-H center dot center dot center dot O interactions between the chains.
引用
收藏
页码：M225 / +
页数：12
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