CATION-RADICAL MECHANISMS OF CATALYTIC HYDROCARBON CONVERSIONS - ISOMERIZATION OF ALKENES

被引：0
|
作者：
VISHNETSKAYA, MV
ROMANOVSKII, BV
机构：
[1] M.V. Lomonosov Moscow State Univ, Moscow, Russia
来源：
PETROLEUM CHEMISTRY | 1993年 / 33卷 / 04期
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An examination has been made of single-electron transfer from a substrate molecule to the catalyst and the formation of a cation-radical as the first stage of alkene isomerization. Within the framework of this model, the stereospecificity of the reaction and the formation of cis-isomers as primary isomerization products are explained. as well as data on deuterated exchange.
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页码：299 / 302
页数：4
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