THE REACTIONS OF 1,2,3-DIAZAPHOSPHOLE DERIVATIVES WITH CATECHOL

被引：3
|
作者：
CHEN, RY
CAI, BZ
机构：
[1] Institute of Elemento-Organic Chem, Nankai Univ, Tianjin, P. R.
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1991年 / 57卷 / 1-2期
关键词：
1,2,3-DIAZAPHOSPHOLE; REACTION; CATECHOL; MECHANISM; CLEAVAGE;
D O I：
10.1080/10426509108038834
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Both two-coordinated phosphorus compounds P=CH-C (Me)=N-NR (1, R=Ph, C (=0) CH3) and tri-coordinated phosphorus compounds R-P-CH2-C (Me)=N-N-C (=O) CH, (2, R=C1, OEt) reacted with catechol in the presence of triethylamine to yield hexa-coordinated phosphorus compound R3P⊖H⊕N (Et) 3 (3, R=-O-C6H4-O-). 3 were confirmed by elemental analysis, IR, 3IP NMR and MS. The mechanism of these reactions was suggested. © 1991 Taylor & Francis Group, LLC. All rights reserved.
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页码：83 / 85
页数：3
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