SYNTHESIS AND CRYSTAL-STRUCTURE OF A QUINOLINOLATO-COMPLEX OF DICYCLOPENTYLGALLIUM

被引：8
|
作者：
TAO, WT
HAN, Y
HUANG, YZ
JIN, XL
SUN, J
机构：
[1] BEIJING UNIV,DEPT CHEM,BEIJING 100871,PEOPLES R CHINA
[2] WUHAN UNIV,DEPT CHEM,WUCHANG 430072,PEOPLES R CHINA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 05期
关键词：
D O I：
10.1039/dt9930000807
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tricyclopentylgallium reacts with 8-hydroxyquinoline in 1:1 ratio to yield quantitatively bis[dicyclo-pentyl(quinolin-8-olato)gallium] which has been characterized by elemental analysis, IR, H-1 NMR and mass spectrometry. X-Ray diffraction analysis indicated that the compound belongs to the triclinic system, space group P1BAR, with a = 10.591(4), b = 12.065(4), c = 13.941(4) angstrom, alpha = 81.92(2), beta = 87.83(3), gamma = 82.55(3)-degrees, Z = 2 (dimers), R = 0.0608 (R' = 0.0871 ). The molecule contains an oxygen-bridged coplanar Ga2O2 four-membered ring.
引用
收藏
页码：807 / 809
页数：3
相关论文
共 50 条
  • [41] ON RUBIDIUM OZONIDE - SYNTHESIS AND CRYSTAL-STRUCTURE
    SCHNICK, W
    JANSEN, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1986, 532 (01): : 37 - 46
  • [42] DIAZABORACYCLOPROPANES - SYNTHESIS AND CRYSTAL-STRUCTURE ANALYSIS
    BOESE, R
    KLINGEBIEL, U
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 306 (03) : 295 - 302
  • [43] SYNTHESIS AND CRYSTAL-STRUCTURE OF TETRAMETHYLAMMONIUM ACETATOTRIMETHYLALUMINATE
    ATWOOD, JL
    HUNTER, WE
    CRISSINGER, KD
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 127 (03) : 403 - 414
  • [44] SYNTHESIS AND CRYSTAL-STRUCTURE OF DIIODOTETRAETHYLTHIURAMDISULFIDEMERCURY(II)
    CHIEH, C
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (07): : 1115 - 1119
  • [45] SYNTHESIS AND CRYSTAL-STRUCTURE OF PENTABENZYLCYCLOPENTADIENYLINDIUM(I)
    SCHUMANN, H
    JANIAK, C
    GORLITZ, F
    LOEBEL, J
    DIETRICH, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 363 (03) : 243 - 251
  • [46] THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A TANTALUM METALLOCYCLOPENTADIENE
    HOLMES, RS
    WIGLEY, DE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 77 - CHED
  • [47] NEW SYNTHESIS AND CRYSTAL-STRUCTURE OF LEUCROSE
    THIEM, J
    KLEEBERG, M
    KLASKA, KH
    CARBOHYDRATE RESEARCH, 1989, 189 : 65 - 77
  • [48] SYNTHESIS AND CRYSTAL-STRUCTURE OF THIOSEMICARBAZIDEDICHLOROMERCURY (II)
    CHIEH, C
    COWELL, DH
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (22): : 3898 - 3900
  • [49] CYCLODISALAZANE CATIONS - SYNTHESIS AND CRYSTAL-STRUCTURE
    KLIEBISCH, U
    KLINGEBIEL, U
    STALKE, D
    SHELDRICK, GM
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (10): : 915 - 916
  • [50] SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF A TRIMETALLIC DIPORPHYRIN COMPLEX
    WOO, LK
    MAURYA, MR
    JACOBSON, RA
    RINGROSE, SL
    INORGANICA CHIMICA ACTA, 1993, 212 (1-2) : 337 - 340
12345