ANION-DEPENDENT AND SOLVENT-DEPENDENT PHOTOCHEMICAL DECOMPLEXATION OF SODIUM-SALT COMPLEXES OF A CALIX[4]ARENE TETRAESTER

被引:7
|
作者
BARRETT, G
CORRY, D
CREAVEN, BS
JOHNSTON, B
MCKERVEY, MA
ROONEY, A
机构
[1] NATL UNIV IRELAND UNIV COLL CORK,DEPT CHEM,CORK,IRELAND
[2] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND
关键词
D O I
10.1039/c39950000363
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sodium salt complexes of p-tert-butylcalix[4]arene tetraethyl acetate, where the anion is iodide, bromide, thiocyanate, perchlorate, tetraphenylborate, tetrafluoroborate or hexafluoroantimonate undergo a solvent-dependent decomplexation when irradiated with a low-pressure mercury lamp; photocleavage or photoisomerisation of the calixarene is not observed.
引用
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页码:363 / 364
页数:2
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