SYNTHESIS BASED ON CYCLOHEXADIENES .9. TOTAL SYNTHESIS OF (PLUS-OR-MINUS)-SEYCHELLENE

被引：10
|
作者：
RAO, GSRS
BHASKAR, KV
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 22期
关键词：
D O I：
10.1039/p19930002813
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new strategy for the total synthesis of (+/-)-seychellene 1 is described. The key step is an intramolecular Michael addition involving a 6-exo cyclisation with a vinyl radical derived from the acetylenic compound 11, obtained from the bicyclo[2.2.2]octene adduct 5 to the tricyclic intermediates 14 and 15.
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页码：2813 / 2816
页数：4
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