FTIR PRODUCT STUDY OF THE REACTION OF CH3OCH2O2+HO2

被引：74
|
作者：
WALLINGTON, TJ [1 ]
HURLEY, MD [1 ]
BALL, JC [1 ]
JENKIN, ME [1 ]
机构：
[1] UKAEA, CONSULTANCY SERV, HARWELL LAB, CHEM KINET SECT, DIDCOT OX11 0RA, OXON, ENGLAND
来源：
CHEMICAL PHYSICS LETTERS | 1993年 / 211卷 / 01期
关键词：
D O I：
10.1016/0009-2614(93)80049-U
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Fourier transform infrared spectroscopy was used to identify CH3OCHO and CH3OCH2OOH as products of the gas-phase reaction of CH3OCH2O2 radicals with HO2 radicals. At 700 Torr and 295 +/- 2 K, branching ratios of k1a/k1 = 0.53 +/- 0.08 and k1b/k1 = 0.40 +/- 0.04 were established. Quoted errors are 2 standard deviations together with our estimate of systematic uncertainties. (CH3OCH2O2+HO2-->CH3OCH2OOH+O2 (1a), CH3OCH2O2+HO2-->CH3OCHO+O2+ H2O (1b).) This result is discussed with respect to previous literature data and to computer models of atmospheric chemistry. As part of this work, the rate constants for the reaction of Cl atoms with CH3OCH2OOH and CH3OCHO were determined to be (6.1 +/- 0.3) x 10(-11) and (1.4 +/- 0.1) x 10(-12) cm3 molecule-1 s-1, respectively.
引用
收藏
页码：41 / 47
页数：7
相关论文
共 50 条
  • [21] Is the CH2OH+O2 → CH2=O+HO2 reaction barrierless?: an ab initio study on the reaction mechanism
    Ramirez-Ramirez, Victor M.
    Serrano-Andres, Luis
    Nebot-Gil, Ignacio
    THEORETICAL CHEMISTRY ACCOUNTS, 2006, 116 (4-5) : 637 - 640
  • [22] Ab Initio Unimolecular Reaction Kinetics of CH2C(=O)OCH3 and CH3C(=O)OCH2 Radicals
    Tan, Ting
    Yang, Xueliang
    Ju, Yiguang
    Carter, Emily A.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (42): : 10553 - 10562
  • [23] A systematic computational study on the reactions of HO2 with RO2:: The HO2+CH3O2(CD3O2) and HO2+CH2FO2 reactions
    Hou, H
    Wang, BS
    JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (03): : 451 - 460
  • [24] Is the CH2OH + O2 → CH2 = O + HO2 Reaction Barrierless? An Ab Initio Study on the Reaction Mechanism
    Víctor M. Ramírez-Ramírez
    Luis Serrano-Andrés
    Ignacio Nebot-Gil
    Theoretical Chemistry Accounts, 2006, 116 : 637 - 640
  • [25] FTIR PRODUCT STUDY OF THE SELF-REACTION OF CH2CLCH2O2 RADICALS IN AIR AT 295-K
    WALLINGTON, TJ
    ANDINO, JM
    JAPAR, SM
    CHEMICAL PHYSICS LETTERS, 1990, 165 (2-3) : 189 - 194
  • [26] CHEMISTRY AND STRUCTURE OF THE CH3O2+ PRODUCT OF THE O-2++CH4 REACTION
    VANDOREN, JM
    BARLOW, SE
    DEPUY, CH
    BIERBAUM, VM
    DOTAN, I
    FERGUSON, EE
    JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (12): : 2772 - 2777
  • [27] The Cl-initiated oxidation of CH3C(O)OCH=CH2, CH3C(O)OCH2CH=CH2, and CH2=CHC(O)O(CH2)3CH3 in the troposphere
    María B. Blanco
    Iustinian Bejan
    Ian Barnes
    Peter Wiesen
    Mariano A. Teruel
    Environmental Science and Pollution Research, 2009, 16 : 641 - 648
  • [28] The Cl-initiated oxidation of CH3C(O)OCH=CH2, CH3C(O)OCH2CH=CH2, and CH2=CHC(O)O(CH2)3CH3 in the troposphere
    Blanco, Maria B.
    Bejan, Iustinian
    Barnes, Ian
    Wiesen, Peter
    Teruel, Mariano A.
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2009, 16 (06) : 641 - 648
  • [29] NI(OCH2CH2OCH2CH3)2 AND THE PREPARATION OF NITIO3
    SCHMIDT, F
    FELTZ, A
    ZEITSCHRIFT FUR CHEMIE, 1990, 30 (06): : 228 - 229
  • [30] Atmospheric chemistry of dimethoxymethane (CH3OCH2OCH3): Kinetics and mechanism of its reaction with OH radicals and fate of the alkoxy radicals CH3OCHO(&middot)OCH3 and CH3OCH2OCH2O(&middot)
    Ford Motor Co, Dearborn, United States
    J Phys Chem A, 29 (5302-5308):
12345