DEACTIVATION OF 2-PHOTON-EXCITED XE(5P(5)6P,6P',7P) AND KR(4P(5)5P) IN XENON AND KRYPTON

被引：39

作者：

WHITEHEAD, CA

POURNASR, H

BRUCE, MR

CAI, H

KOHEL, J

LAYNE, WB

KETO, JW

机构：

[1] Physics Department, University of Texas at Austin, Austin

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 102卷 / 05期

关键词：

D O I：

10.1063/1.468763

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lifetimes and bimolecular quenching rate constants have been determined for two-photon laser excited states ofXe*(5p56p, 5p 56p′,5p57p) and Kr*(4p55p) in krypton and xenon buffer gases. Collisional mixing between Kr*5p[5/2] 2 and Kr*5p[5/2]3 in krypton is observed and analyzed using a coupled two-state model to obtain the rate of mixing. The measured rate constants for quenching of Xe*(6p′ ,7p) by krypton are 15%-20% smaller than those measured previously in xenon while bimolecular rates for the Kr*(5p) states are an order of magnitude larger in xenon than those in a krypton buffer. Measurements of state-to-state rate constants for deactivation and excitation transfer are also reported for these states in krypton and xenon buffer gases. © 1995 American Institute of Physics.

引用

页码：1965 / 1980

页数：16

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