DICHLORO(2,6-DIACETYLPYRIDINE DIOXIME-KAPPA(3)N,N',N'')COPPER(II) 1.5-HYDRATE

被引：10
|
作者：
ABBOUD, KA
PALENIK, RC
PALENIK, GJ
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S0108270193009746
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of hydroxylamine with aquachloro(2,6-diacetylpyridine disemicarbazone)copper(II) results in a displacement of the semicarbazide group and the formation of dichloro(2,6-diacetylpyridine dioxime-kappa3N,N',N'')copper(II) 1.5-hydrate {[CuCl2-(C9H11N3O2)]2.3H2O}. A triclinic dihydrate form has been reported previously. The Cu atom is in the center of a square pyramid consisting of a Cl and three N atoms in the base and an apical Cl. An analysis of the five-coordinate CuCl2N3 structures in the 1992 release of the Cambridge Crystallographic Database revealed a linear relationship between the displacement of the Cu atom from the basal plane and the apical Cu-Cl distance.
引用
收藏
页码：525 / 528
页数：4
相关论文
共 50 条
  • [21] PHOSPHORESCENCE EMISSION OF 2,6-DIACETYLPYRIDINE - ROLE OF N-HETEROATOM AND EFFECT OF HYDROGEN-BONDING
    SARKAR, SK
    GANGULY, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (08) : 2372 - 2377
  • [22] Dichloro(N-cyclohexyl-N,N′,N′-trimethylethylenediamine-κ2N,N′)copper(II)
    Johansson, A
    Håkansson, M
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1068 - M1070
  • [23] N-(p-tolyl)-β-L-rhamnopyranosylamine 1.5-hydrate
    Punzo, F
    Watkin, DJ
    Cook, JMD
    Hotchkiss, D
    Fleet, GWJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O2155 - O2157
  • [24] Aquabis(3-chlorobenzoato-kappa O)bis(N,N-diethylnicotinamide-kappa N)copper(II)
    Bozkurt, Nihat
    Tunc, Tuncay
    Delibas, Nagihan Caylak
    Necefoglu, Hacali
    Hokelek, Tuncer
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M458 - +
  • [25] STRUCTURE OF BIS(2,6-DINITROPHENOLATO)(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)
    ZANIN, IE
    ANTIPIN, MY
    SIMONOV, YA
    YAMPOLSKAYA, MA
    STRUCHKOV, YT
    ZHURNAL NEORGANICHESKOI KHIMII, 1991, 36 (10): : 2509 - 2513
  • [26] SYNTHESIS AND CHARACTERIZATION OF TERNARY L-HISTIDINE COMPLEXES - CRYSTAL-STRUCTURE OF (2,2'-DIPYRIDYL)-(L-HISTIDINATO-N,N',O)COPPER(II) PERCHLORATE 1.5-HYDRATE
    ABDELRAHMAN, LH
    BATTAGLIA, LP
    SGARABOTTO, P
    MAHMOUD, MR
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1994, 24 (09) : 567 - 571
  • [27] [Bis(quinolin-2-ylcarbonyl)amido-kappa N-3,N ',N '']bromido(N,N-dimethylformamide-kappa O)copper(II)
    Faizi, Md. Serajul Haque
    Sen, Pratik
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M206 - +
  • [28] DETERMINATION OF METAL-IONS COMPLEXED WITH 2,6-DIACETYLPYRIDINE BIS(N-METHYLENEPYRIDINIOHYDRAZONE) BY CAPILLARY ELECTROPHORESIS
    TIMERBAEV, AR
    SEMENOVA, OP
    BONN, GK
    FRITZ, JS
    ANALYTICA CHIMICA ACTA, 1994, 296 (02) : 119 - 128
  • [29] Preparation of [C,N,O]-pincer osmium complexes by alkylidene metathesis with a methyl group of 2,6-diacetylpyridine
    Castarlenas, Ricardo
    Esteruelas, Miguel A.
    Onate, Enrique
    ORGANOMETALLICS, 2007, 26 (13) : 3082 - 3084
  • [30] COMPLEXES OF LIGANDS PROVIDING ENDOGENOUS BRIDGES .4. COPPER(II) COMPLEXES OF MACROCYCLIC SCHIFF-BASES DERIVED FROM 2,6-DIACETYLPYRIDINE AND 1,N-DIAMINO-N'-HYDROXYALKANES (N,N' = 3,2 - 4,2 - AND 5,3) - SYNTHESIS, PROPERTIES, AND STRUCTURES
    BAILEY, NA
    FENTON, DE
    MOODY, R
    DEBARBARIN, COR
    SCIAMBARELLA, IN
    LATOUR, JM
    LIMOSIN, D
    MCKEE, V
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11): : 2519 - 2529
12345