Dichlorido(N,N-diethy1-4-{[(quinolin-2yl)methylidene[amino- k(2)N,N'}aniline)-mercury(11)

被引：10
|
作者：
Faizi, Md. Serajul Haque [1 ]
Hussain, Sahid [2 ]
机构：
[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Indian Inst Technol Patna, Dept Chem, Patna 800013, Bihar, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S160053681400957X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the mononuclear title complex, [HgC12(C20H21N3)], synthesized from the quinoline-derived Schiff base Ni,Ni-diethyl-N-4(quinolin-2-ylmethylidene)benzene-1,4-diamine (QMBD), the coordination geometry around the Hg2+ atom is distorted tetrahedral, comprising two Cl atoms [Hg-Cl = 2.3654 (19) and 2.4394 (18) angstrom] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg-N = 2.334 (5) and 2.340 (5) angstrom, respectively]. In the crystal, weak C-H center dot center dot center dot Cl hydrogen bonds and weak pi-pi aromatic ring stacking interactions [minimum ring-centroid separation 3.680 (4) angstrom] give an overall three-dimensional network.
引用
收藏
页码：M197 / +
页数：9
相关论文
共 50 条
  • [11] 2-Ethyl-N-[(5-nitrothiophen-2-yl)methylidene]aniline
    Ceylan, Umit
    Tanak, Hasan
    Gumus, Sumeyye
    Agar, Erbil
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2004 - U236
  • [12] 4-Methoxy-N-[(E)-(5-nitrothiophen-2-yl)methylidene] aniline
    Akbal, Tufan
    Agar, Erbil
    Gumus, Sumeyye
    Erdonmez, Ahmet
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3026 - +
  • [13] (E)-4-Methyl-N-[(5-nitrothiophen-2-yl)-methylidene]aniline
    Ceylan, Umit
    Gumus, Sumeyye
    Agar, Erbil
    Soylu, Mustafa Serkan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2116 - +
  • [14] (E)-2,4,6-Trimethyl-N-[(1H-pyrro1-2-yl)-methylidene]aniline
    Imhof, Wolfgang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O113 - +
  • [15] (E)-3-Chloro-N-[(2-ethoxynaphthalen-1-yl)methylidene]aniline
    Vesek, Hilal
    Kazak, Canan
    Agar, Aysen Alaman
    Macit, Mustafa
    Soylu, Mustafa Serkan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02518 - +
  • [16] Crystal structures and Hirshfeld surface analysis of trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ2N,N'}manganese(II) and trans-bis(thiocyanato-κN)bis{2,4,6-trimethyl-N-[(pyridin-2-yl)methylidene]aniline-κ2N,N'}nickel(II))
    Jittirattanakun, Siripak
    Theppitak, Chatphorn
    Wannarit, Nanthawat
    Rotsut, Bachari
    Chainok, Kittipong
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 288 - +
  • [17] Crystal structure of trans-bis{4-bromo-N-[(pyridin-2-yl) methylidene] aniline-kappa(2) N, N'} dichloridoruthenium(II)
    Chainok, Kittipong
    Kielar, Filip
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 1067 - +
  • [18] N′-[(2-Methoxynaphthalen-1-yl)methylidene]-4-methylbenzohydrazide
    Meng, Xu-Feng
    Wang, Dong-Yue
    Ma, Jing-Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3109 - U2077
  • [19] Crystal structure of dibromido(N,N-dimethylformamide-kappa O){2-(1H-indol-3-yl)N-[(quinolin-2-yl-kappa N) methylidene]ethanamine-kappa N}cadmium
    Faizi, Md. Serajul Haque
    Sharkina, Natalia O.
    Davydenko, Yuliya M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M31 - U141
  • [20] N′-[(2-Hydroxynaphthalen-1-yl)methylidene]-4-nitrobenzohydrazide
    An, Yan
    Li, Xiaofeng
    Zhang, Yingjie
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3278 - U917
12345