Dichlorido(N,N-diethy1-4-{[(quinolin-2yl)methylidene[amino- k(2)N,N'}aniline)-mercury(11)

被引：10
|
作者：
Faizi, Md. Serajul Haque [1 ]
Hussain, Sahid [2 ]
机构：
[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Indian Inst Technol Patna, Dept Chem, Patna 800013, Bihar, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S160053681400957X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the mononuclear title complex, [HgC12(C20H21N3)], synthesized from the quinoline-derived Schiff base Ni,Ni-diethyl-N-4(quinolin-2-ylmethylidene)benzene-1,4-diamine (QMBD), the coordination geometry around the Hg2+ atom is distorted tetrahedral, comprising two Cl atoms [Hg-Cl = 2.3654 (19) and 2.4394 (18) angstrom] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg-N = 2.334 (5) and 2.340 (5) angstrom, respectively]. In the crystal, weak C-H center dot center dot center dot Cl hydrogen bonds and weak pi-pi aromatic ring stacking interactions [minimum ring-centroid separation 3.680 (4) angstrom] give an overall three-dimensional network.
引用
收藏
页码：M197 / +
页数：9
相关论文
共 50 条
  • [1] Dichlorido(4-{[(quinolin-2-yl) methylidene]amino}phenol-kappa(2) N,N ')mercury(II)
    Faizi, Md. Serajul Haque
    Sen, Pratik
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M173 - +
  • [2] Crystal structure of dichlorido{N-1-phenyl-N-4-[(quinolin-2-yl-kappa N)methylidene]-benzene-1,4-diamine-kappa N-4}mercury(II)
    Faizi, Md. Serajul Haque
    Prisyazhnaya, Elena V.
    Iskenderov, Turganbay S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M46 - U221
  • [3] 2,6-Diisopropyl-N-[(Z)-quinolin-2-yl-methylidene]aniline
    Sood, Anjali
    Raisanen, Minna T.
    Ahlgren, Markku
    Leskela, Markku
    Repo, Timo
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4083 - U3364
  • [4] Dichlorido{N-[(5-methylthiophen-2-yl)methylidene]-2-(pyridin-2-yl)ethanamine-k(2)N,N '}palladium(II)
    Radebe, Mduduzi P.
    Onani, Martin O.
    Motswainyana, William M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M20 - +
  • [5] Dichlorido{(E)-2,4,6-trimethyl-N-[phenyl(2-pyridyl)methylidene]aniline-κ2N,N′}palladium(II)
    Yang, Cheng-Hsien
    Peng, Ya-Liu
    Wang, Mei-Hua
    Shih, Kuo-Chen
    Hsueh, Mao-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M633 - U382
  • [6] Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ2N′,O}copper(II)
    Datta, Amitabha
    Sheu, Shiann-Cherng
    Liu, Pei-Hsin
    Huang, Jui-Hsien
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1852 - U1232
  • [7] Dichlorido{N '-[phenyl(pyridin-2-yl-kappa N)-methylidene]isonicotinohydrazide-kappa N-2 ',O}zinc
    Sy, Adama
    Dieng, Moussa
    Thiam, Ibrahima Elhadj
    Gaye, Mohamed
    Retailleau, Pascal
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M108 - +
  • [8] Crystal structure of N-1, N-1-diethyl-N-4-[(quinolin-2-yl)methylidene]benzene-1,4-diamine
    Faizi, Md. Serajul Haque
    Siddiqui, Nazia
    Javed, Saleem
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O49 - +
  • [9] 4-Methyl-N-[(5-nitrothiophen-2-yl)methylidene]aniline
    Cai, Mingjian
    Wang, Xiuge
    Sun, Tao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2218 - U1587
  • [10] Crystal structure of N-1-phenyl-N-4-[(quinolin-2-yl)methylidene]benzene-1,4diamine
    Faizi, Md. Serajul Haque
    Mashrai, Ashraf
    Garandal, Saleem
    Shahid, M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O905 - +
12345