HOMOLYTIC OXOALKYLATION OF PROTONATED N-HETEROAROMATIC COMPOUNDS

被引：3

作者：

KAPUSTINA, NI

SOKOVA, LL

IGNATENKO, AV

NIKISHIN, GI

机构：

[1] N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 11期

关键词：

HOMOLYTIC OXOALKYLATION; HETEROAROMATIC BASES; LEAD TETRAACETATE; MANGANESE TRIACETATE; PYRIDINE; QUINOLINE; 1-METHYLCYCLOBUTANOL; 1-METHYLCYCLOPENTANOL;

D O I：

10.1007/BF00698999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxoalkylation of pyridine, 2-methyl-, 4-methyl-, 2,4-dimethyl-, 2,6-dimethyl-pyridines, quinoline, 4-methylquinoline, isoquinoline, and pyrazine with oxoalkyl radicals generated from 1-methylcyclobutanol or 1-methylcyclopentanol under the action of Pb(OAc)4 or Mn(OAc)3 has been carried out. The reaction products are isomers with 2-(6)- and 4-positions of the oxoalkyl group in the N-heteroaromatic ring. The isomer ratios have been determined as a function of the structure of the N-heteroaromatic compound and the reaction conditions.

引用

页码：1839 / 1843

页数：5

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